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• W3048888919 endingPage "418" @default.
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• W3048888919 abstract "Transparent-conductive-oxide-free (T-C-O-free) back-contact (B-C) dye-sensitized solar cell (DSC) utilizing flexible Stainless Steel (SS) mesh (SS-mesh) supported with mesoporous TiO2 as a photoanode employing cobalt electrolyte is being presented. A thin layer of Ti metal over the SS-mesh was ascertained to be essential to retard the back electron reaction, which was confirmed by the dark current measurements. The interfacial contact between the SS-mesh and nanoporous (NP) TiO2 of the photoanode of T-C-O-free B-C-DSC was driven to influence the photovoltaic performance greatly. It was confirmed by electrochemical impedance analysis that NP TiO2 of 30 nm exhibited less charge transfer impedance observed at TiO2-dye-electrolyte interface as compared to TiO2 of having particle size of 15–20 nm. T-C-O-free B-C-DSC employing dye mixer combination of indoline dyes D-131 and D-205 (1:1) with relatively larger NP of TiO2 (30 nm) as compared to TiO2 of 15–20 nm exhibited enhanced photoconversion efficiency (PCE) of 4.02%. To increase the PCE even further, T-C-O-free B-C-DSC with cobalt based electrolyte sensitized with porphyrin (YD2-o-C8)-dye bearing a larger optical window was investigated. An optimized 10 µm thickness of the TiO2 layer was found to be optimum leading to an enhanced PCE of 5.26%." @default.
• W3048888919 created "2020-08-18" @default.
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• W3048888919 date "2020-09-01" @default.
• W3048888919 modified "2023-09-24" @default.
• W3048888919 title "Parametric optimization of back-contact T-C-O-free dye-sensitized solar cells employing indoline and porphyrin sensitizer based on cobalt redox electrolyte" @default.
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• W3048888919 doi "https://doi.org/10.1016/j.solener.2020.08.011" @default.
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