Matches in SemOpenAlex for { <https://semopenalex.org/work/W3048893929> ?p ?o ?g. }
- W3048893929 endingPage "118814" @default.
- W3048893929 startingPage "118814" @default.
- W3048893929 abstract "An easy and selective method has been developed for the extractive spectrophotometric determination of ruthenium(III) with 4-(4'-flurobenzylideneimino)-3-methyl-5-mercapto-1,2,4-triazole (FBIMMT) as a chelating reagent. The basis of the method is the formation of stable complex of 'soft base' FBIMMT with 'soft acid' ruthenium(III). The reagent FBIMMT in n-butanol easily forms extractable yellow coloured complex with ruthenium(III) in acetate buffer of pH 4.8. The absorbance of [Ru(III)-FBIMMT] complex is measured at 394 nm against the reagent blank. Good linearity range of concentration up to 27.0 μg mL-1 of ruthenium(III) is attained with correlation coefficient R2 = 0.998. The optimum concentration range is 6 to 27.0 μg mL-1 which is deduced by Ringbom's plot. The apparent molar absorptivity found to be 2.75 × 103 L mol-1 cm-1. Some additional characteristics such as limit of detection (LOD = 0.48 μg mL-1), limit of quantification (LOQ = 1.19 μg mL-1), and Sandell's sensitivity (SS = of 0.0367 μg cm-2) are also estimated. The composition of [Ru(III)-FBIMMT] complex has been established from Job's continuous variation method, mole ratio method, and log-log plot method. The specificity towards ruthenium(III) is well studied and appropriate masking agents are applied wherever required to boost it. The intra-day and inter-day precision values are found to be brilliant with % relative standard deviation of 0.52 and 0.68 respectively with % accuracy within the range of 99.00-100. The method is effectively used for determination of ruthenium(III) from water samples, binary and ternary synthetic mixtures, fissium alloy samples and catalyst materials. A scheme for sequential group separation of ruthenium(III), palladium(II) and osmium(VIII) has also been developed. The reproducible results of the present method confirm that the method has a good potential for quantitative determination of ruthenium(III) from various matrices." @default.
- W3048893929 created "2020-08-18" @default.
- W3048893929 creator A5003503967 @default.
- W3048893929 creator A5006772292 @default.
- W3048893929 creator A5024951190 @default.
- W3048893929 creator A5044341661 @default.
- W3048893929 creator A5064894552 @default.
- W3048893929 creator A5072697972 @default.
- W3048893929 creator A5082934827 @default.
- W3048893929 date "2020-12-01" @default.
- W3048893929 modified "2023-09-25" @default.
- W3048893929 title "Highly reproducible, simple and selective analytical method for extractive UV–visible spectrophotometric determination of ruthenium(III): Analysis of catalyst, fissium alloy and sequential separation" @default.
- W3048893929 cites W1823846556 @default.
- W3048893929 cites W1965709612 @default.
- W3048893929 cites W1966584737 @default.
- W3048893929 cites W1966752004 @default.
- W3048893929 cites W2005877813 @default.
- W3048893929 cites W2014787895 @default.
- W3048893929 cites W2026909417 @default.
- W3048893929 cites W2027347947 @default.
- W3048893929 cites W2030114408 @default.
- W3048893929 cites W2033040322 @default.
- W3048893929 cites W2033647577 @default.
- W3048893929 cites W2035708477 @default.
- W3048893929 cites W2051704540 @default.
- W3048893929 cites W2064305654 @default.
- W3048893929 cites W2064881417 @default.
- W3048893929 cites W2064907650 @default.
- W3048893929 cites W2066825427 @default.
- W3048893929 cites W2093049133 @default.
- W3048893929 cites W2120469173 @default.
- W3048893929 cites W2127016166 @default.
- W3048893929 cites W2157338975 @default.
- W3048893929 cites W223158690 @default.
- W3048893929 cites W2289981813 @default.
- W3048893929 cites W2557326043 @default.
- W3048893929 cites W2751103430 @default.
- W3048893929 cites W2799821412 @default.
- W3048893929 cites W2892100842 @default.
- W3048893929 cites W2906402560 @default.
- W3048893929 cites W2943406693 @default.
- W3048893929 cites W2968360754 @default.
- W3048893929 cites W3035929884 @default.
- W3048893929 cites W316170815 @default.
- W3048893929 cites W4242454585 @default.
- W3048893929 doi "https://doi.org/10.1016/j.saa.2020.118814" @default.
- W3048893929 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32861203" @default.
- W3048893929 hasPublicationYear "2020" @default.
- W3048893929 type Work @default.
- W3048893929 sameAs 3048893929 @default.
- W3048893929 citedByCount "5" @default.
- W3048893929 countsByYear W30488939292022 @default.
- W3048893929 countsByYear W30488939292023 @default.
- W3048893929 crossrefType "journal-article" @default.
- W3048893929 hasAuthorship W3048893929A5003503967 @default.
- W3048893929 hasAuthorship W3048893929A5006772292 @default.
- W3048893929 hasAuthorship W3048893929A5024951190 @default.
- W3048893929 hasAuthorship W3048893929A5044341661 @default.
- W3048893929 hasAuthorship W3048893929A5064894552 @default.
- W3048893929 hasAuthorship W3048893929A5072697972 @default.
- W3048893929 hasAuthorship W3048893929A5082934827 @default.
- W3048893929 hasConcept C113196181 @default.
- W3048893929 hasConcept C119128265 @default.
- W3048893929 hasConcept C120665830 @default.
- W3048893929 hasConcept C121332964 @default.
- W3048893929 hasConcept C14538495 @default.
- W3048893929 hasConcept C161790260 @default.
- W3048893929 hasConcept C178790620 @default.
- W3048893929 hasConcept C185592680 @default.
- W3048893929 hasConcept C2780343419 @default.
- W3048893929 hasConcept C40875361 @default.
- W3048893929 hasConcept C43617362 @default.
- W3048893929 hasConcept C555196967 @default.
- W3048893929 hasConcept C76046532 @default.
- W3048893929 hasConcept C89838059 @default.
- W3048893929 hasConcept C98015330 @default.
- W3048893929 hasConceptScore W3048893929C113196181 @default.
- W3048893929 hasConceptScore W3048893929C119128265 @default.
- W3048893929 hasConceptScore W3048893929C120665830 @default.
- W3048893929 hasConceptScore W3048893929C121332964 @default.
- W3048893929 hasConceptScore W3048893929C14538495 @default.
- W3048893929 hasConceptScore W3048893929C161790260 @default.
- W3048893929 hasConceptScore W3048893929C178790620 @default.
- W3048893929 hasConceptScore W3048893929C185592680 @default.
- W3048893929 hasConceptScore W3048893929C2780343419 @default.
- W3048893929 hasConceptScore W3048893929C40875361 @default.
- W3048893929 hasConceptScore W3048893929C43617362 @default.
- W3048893929 hasConceptScore W3048893929C555196967 @default.
- W3048893929 hasConceptScore W3048893929C76046532 @default.
- W3048893929 hasConceptScore W3048893929C89838059 @default.
- W3048893929 hasConceptScore W3048893929C98015330 @default.
- W3048893929 hasLocation W30488939291 @default.
- W3048893929 hasLocation W30488939292 @default.
- W3048893929 hasOpenAccess W3048893929 @default.
- W3048893929 hasPrimaryLocation W30488939291 @default.
- W3048893929 hasRelatedWork W1559344862 @default.
- W3048893929 hasRelatedWork W1989627846 @default.
- W3048893929 hasRelatedWork W2043018397 @default.