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• W3048904537 startingPage "104266" @default.
• W3048904537 abstract "Temperature measurement on propagating flame and minimum explosible concentration are investigated. The dust explosion experiments of nano-particle dust clouds exhibit higher temperature gradient in preheat zone and lower MEC than those of micron particle dust clouds. A heterogeneous model is proposed to describe the oxidation process under two extreme conditions: whether the alumina film is involved in the reaction or not. The new methodology allows the estimation of oxidation kinetics of growing alumina. For micron particle, the model clarifies that the activation energy which has been wrongly considered to be for aluminum oxidation should be for lattice diffusion, and the initial reaction rate is proved to be dominated by the diffusion rate of oxygen through alumina shell as diffusion controlled reaction. For nano-particle, the model explained that why the reported activation energy shows significantly lower than that for micron particle, due to initially ignorable alumina film or considered as kinetically controlled reaction. However, as reaction occurs and alumina builds up on the surface, the interference of alumina somewhat increases the activation energy." @default.
• W3048904537 created "2020-08-18" @default.
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• W3048904537 date "2020-11-01" @default.
• W3048904537 modified "2023-10-02" @default.
• W3048904537 title "Flame propagation through dust clouds of nano and micron scale aluminum particles" @default.
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• W3048904537 doi "https://doi.org/10.1016/j.jlp.2020.104266" @default.
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