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- W3048954476 abstract "Abstract The third spectrum of bismuth (Bi III) with its ground configuration 5d106s26p has been investigated in the wavelength region 278-2000 A using spectrograms recorded on a 3-m normal incidence vacuum spectrograph. The observed spectrum was interpreted using semi-empirical calculations with Cowan's code in the framework of the quasi-Relativistic Hartree-Fock method. Analyses made by previous investigators on one and three-electron systems were checked thoroughly, while the tentative identification of the 2S1/2 level of the 5d106s6p2 configuration is confirmed. For the first time we had investigated the 6p3, 6s6p6d and 6s6p7s odd configurations based on the identification of 99 spectral lines. In total, 67 energy levels are now being established, which belong to the 5d10[6s2np (n=6-8) + 6s2nf (n=5-7) + 6s2nh (n=6-7)], 6s6p2 and 5d96s26p2 configurations, among which 23 energy levels were newly located. The least squares parametric fitting calculations were performed to interpret the final results of the analysis. Optimization of the observed energy levels was carried out with the computer program LOPT. The ionization energy was found to be 206242.0±1.4 cm−1 (25.5708±0.0002 eV)." @default.
- W3048954476 created "2020-08-18" @default.
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- W3048954476 date "2020-11-01" @default.
- W3048954476 modified "2023-10-14" @default.
- W3048954476 title "Revised and extended analysis of doubly ionized bismuth: Bi III" @default.
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- W3048954476 doi "https://doi.org/10.1016/j.jqsrt.2020.107253" @default.
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