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- W3049188674 endingPage "2002914" @default.
- W3049188674 startingPage "2002914" @default.
- W3049188674 abstract "The host-guest chemistry of metal-organic frameworks (MOFs) has enabled the derivation of numerous new functionalities. However, intrinsically chiral MOFs (CMOFs) with helical channels have not been used to realize crystalline circularly polarized luminescence (CPL) materials. Herein, enantiomeric pairs of MOF crystals are reported, where achiral fluorophores adhere to the inner surface of helical channels via biology-like H-bonds and hence inherit the helicity of the host MOFs, eventually amplifying the luminescence dissymmetry factor (glum ) of the host l/d-CMOF (±1.50 × 10-3 ) to a maximum of ±0.0115 for the composite l/d-CMOF⊃fluorophores. l/d-CMOF⊃fluorophores in pairs generate bright color-tunable CPL and almost ideal white CPL (0.33, 0.32) with a record-high photoluminescence quantum yield of ≈30%, which are further assembled into a white circularly polarized light-emitting diode. The present strategy opens a new avenue for propagating the chirality of MOFs to realize universal chiroptical materials." @default.
- W3049188674 created "2020-08-21" @default.
- W3049188674 creator A5005592293 @default.
- W3049188674 creator A5009741300 @default.
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- W3049188674 creator A5050016252 @default.
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- W3049188674 creator A5074960380 @default.
- W3049188674 creator A5077940282 @default.
- W3049188674 creator A5089613888 @default.
- W3049188674 date "2020-08-16" @default.
- W3049188674 modified "2023-10-15" @default.
- W3049188674 title "Enantiomeric MOF Crystals Using Helical Channels as Palettes with Bright White Circularly Polarized Luminescence" @default.
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