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• W3049208345 abstract "The crystal structures of two manganese(I) complexes with ester-substituted bipyridine or biquinoline supporting ligands are reported, namely, fac -bromidotricarbonyl(diethyl 2,2′-bipyridine-4,4′-dicarboxylate-κ 2 N , N ′)manganese(I), [MnBr(C 16 H 16 N 2 O 4 )(CO) 3 ], I , and fac -bromidotricarbonyl(diethyl 2,2′-biquinoline-4,4′-dicarboxylate-κ 2 N , N ′)manganese(I), [MnBr(C 24 H 20 N 2 O 4 )(CO) 3 ], II . In both complexes, the manganese(I) atom adopts a distorted octahedral coordination sphere defined by three carbonyl C atoms, a Br − anion and two N atoms from the chelating α-diimine ligand. Both complexes show fac configurations of the carbonyl ligands. In I , the complex molecules are linked by C—H...Br hydrogen bonds and aromatic π–π contacts. In II , intramolecular C—H...O hydrogen bonds are present as well as intermolecular C—H...O and C—H...Br hydrogen bonds and π–π interactions." @default.
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• W3049208345 date "2020-08-11" @default.
• W3049208345 modified "2023-10-13" @default.
• W3049208345 title "Synthesis and crystal structures of manganese(I) carbonyl complexes bearing ester-substituted α-diimine ligands" @default.
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• W3049208345 doi "https://doi.org/10.1107/s2056989020010750" @default.
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