Matches in SemOpenAlex for { <https://semopenalex.org/work/W3049351566> ?p ?o ?g. }
- W3049351566 endingPage "33" @default.
- W3049351566 startingPage "15" @default.
- W3049351566 abstract "As an emerging oxidant and disinfectant, peracetic acid (PAA) has increasingly been used in wastewater treatment and the food and medical industries and has attracted greater research interest. To better understand reactions initiated by PAA, this paper is among the first to comprehensively review the reactivity of PAA with respect to organic compounds of various structures. The reactivities of PAA with respect to 123 organic compounds are compiled from the literature and new experiments, and possible reaction pathways and products are discussed. Overall, PAA is an electrophile with high selectivity in reaction. The second-order rate constants of PAA oxidation of organic compounds vary by nearly 10 orders of magnitude, from 3.2 × 10–6 to >1.0 × 105 M–1 s–1, which are much larger than those of H2O2 coexisting in PAA solutions. Electron-donating groups of compounds increase the reactivity with respect to PAA, evidenced by the strong negative correlations between rate constants and substituent constants [Hammett (σ) or Taft (σ*)] of compounds. Sulfur moieties show exceptionally high reactivity with respect to PAA. Limited studies have shown that generally oxygen-added reaction products are formed from PAA oxidation. This critical review provides a useful foundation for advancing our understanding of the fate of organic compounds in wastewater treatment including PAA and identifies further research needs to evaluate a broader range of compounds and their oxidation products and toxicity." @default.
- W3049351566 created "2020-08-21" @default.
- W3049351566 creator A5077558661 @default.
- W3049351566 creator A5086451445 @default.
- W3049351566 date "2020-08-13" @default.
- W3049351566 modified "2023-10-16" @default.
- W3049351566 title "Reactivity of Peracetic Acid with Organic Compounds: A Critical Review" @default.
- W3049351566 cites W1128270289 @default.
- W3049351566 cites W1159561502 @default.
- W3049351566 cites W121021299 @default.
- W3049351566 cites W139201533 @default.
- W3049351566 cites W1523676194 @default.
- W3049351566 cites W1555109306 @default.
- W3049351566 cites W1963687054 @default.
- W3049351566 cites W1964203764 @default.
- W3049351566 cites W1969133949 @default.
- W3049351566 cites W1971322610 @default.
- W3049351566 cites W1977298287 @default.
- W3049351566 cites W1977853465 @default.
- W3049351566 cites W1981166602 @default.
- W3049351566 cites W1983858379 @default.
- W3049351566 cites W1984384825 @default.
- W3049351566 cites W1986933128 @default.
- W3049351566 cites W1987900285 @default.
- W3049351566 cites W1989260721 @default.
- W3049351566 cites W1999110319 @default.
- W3049351566 cites W2000298692 @default.
- W3049351566 cites W2002929885 @default.
- W3049351566 cites W2003351729 @default.
- W3049351566 cites W2003475521 @default.
- W3049351566 cites W2005644208 @default.
- W3049351566 cites W2007646437 @default.
- W3049351566 cites W2009163514 @default.
- W3049351566 cites W2012777326 @default.
- W3049351566 cites W2019860390 @default.
- W3049351566 cites W2022063130 @default.
- W3049351566 cites W2023793802 @default.
- W3049351566 cites W2027899818 @default.
- W3049351566 cites W2031384284 @default.
- W3049351566 cites W2034154234 @default.
- W3049351566 cites W2035430147 @default.
- W3049351566 cites W2035790189 @default.
- W3049351566 cites W2036070862 @default.
- W3049351566 cites W2044726239 @default.
- W3049351566 cites W2045207296 @default.
- W3049351566 cites W2049880148 @default.
- W3049351566 cites W2050354748 @default.
- W3049351566 cites W2051476554 @default.
- W3049351566 cites W2053786700 @default.
- W3049351566 cites W2054663689 @default.
- W3049351566 cites W2054890766 @default.
- W3049351566 cites W2055803276 @default.
- W3049351566 cites W2056840435 @default.
- W3049351566 cites W2057796023 @default.
- W3049351566 cites W2058398722 @default.
- W3049351566 cites W2059918255 @default.
- W3049351566 cites W2063989950 @default.
- W3049351566 cites W2064344964 @default.
- W3049351566 cites W2069190498 @default.
- W3049351566 cites W2072102434 @default.
- W3049351566 cites W2072482335 @default.
- W3049351566 cites W2072515981 @default.
- W3049351566 cites W2072724015 @default.
- W3049351566 cites W2073551058 @default.
- W3049351566 cites W2077812121 @default.
- W3049351566 cites W2078938223 @default.
- W3049351566 cites W2079712916 @default.
- W3049351566 cites W2079918265 @default.
- W3049351566 cites W2080922195 @default.
- W3049351566 cites W2082581791 @default.
- W3049351566 cites W2085525548 @default.
- W3049351566 cites W2085668238 @default.
- W3049351566 cites W2086558684 @default.
- W3049351566 cites W2089152022 @default.
- W3049351566 cites W2093029943 @default.
- W3049351566 cites W2098062964 @default.
- W3049351566 cites W2099000233 @default.
- W3049351566 cites W2101146640 @default.
- W3049351566 cites W2112740377 @default.
- W3049351566 cites W2125874297 @default.
- W3049351566 cites W2130500190 @default.
- W3049351566 cites W2138549553 @default.
- W3049351566 cites W2145870145 @default.
- W3049351566 cites W2145875183 @default.
- W3049351566 cites W2159668990 @default.
- W3049351566 cites W2174835131 @default.
- W3049351566 cites W2232848834 @default.
- W3049351566 cites W2259191489 @default.
- W3049351566 cites W2313145845 @default.
- W3049351566 cites W2317419558 @default.
- W3049351566 cites W2318671987 @default.
- W3049351566 cites W2320261999 @default.
- W3049351566 cites W2324077696 @default.
- W3049351566 cites W2331122492 @default.
- W3049351566 cites W2331600229 @default.
- W3049351566 cites W2331706899 @default.
- W3049351566 cites W2331890344 @default.
- W3049351566 cites W2406278038 @default.