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• W3049858705 abstract "CsPbI3 based perovskite solar cells (PSCs) are developing rapidly due to their thermal stability, suitable band gap, and excellent optoelectronic properties. However, the phase transition is a serious problem that cannot be ignored. In this experiment, we use solution and thermal evaporation methods to fabricate high quality CsPbI3 films and explore this material’s induction factors of phase instability. The results show that during the phase transition process in the CsPbI3 film, the Gibbs free energy (intrinsic factor) and polar solvents (extrinsic factors) are in the dominant. Both of them are closely related to the grain size. The larger the grain size is, the higher the vibration entropy is and the lower the stability is itself. On the contrary, the smaller the grain size is, the more grain boundaries there are, and polar solvents (charge transport layer induced) more easily induce a phase transition. Therefore, we concluded that we should obtain a suitable grain size and avoid using polar solvents during the PSCs’ fabrication, which prepares CsPbI3 PSCs with high efficiency and stability." @default.
• W3049858705 created "2020-08-24" @default.
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• W3049858705 date "2020-08-17" @default.
• W3049858705 modified "2023-10-16" @default.
• W3049858705 title "Unveiling the Effects of Intrinsic and Extrinsic Factors That Induced a Phase Transition for CsPbI₃" @default.
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• W3049858705 doi "https://doi.org/10.1021/acsaem.0c01801" @default.
• W3049858705 hasPublicationYear "2020" @default.
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