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• W305382246 abstract "We have developed a simultaneous global fit to the MW, THz, infrared, visible, and UV transitions of all six oxygen isotopologues, (16)O(16)O, (16)O(17)O, (16)O(18)O, (17)O(17)O, (17)O(18)O, (18)O(18)O, with the objective of predicting all transitions below the O((3)P) + O((3)P) dissociation threshold as well as the B(3)Σ(u) (-) state from O((3)P)+O((1)D) within state-of-the-art experimental uncertainty. Here, we report an isotopically invariant Dunham fit for the lowest three electronic states, X(3)Σ(g)(-), a(1)Δ(g), and b(1)Σ(g)(+). Experimental transition frequencies involving these three states of all six O(2) isotopologues were critically reviewed and incorporated into the analysis. For the (16)O(16)O isotopologue, experimental data sample vibrational states v = 0-31 for X(3)Σ(g)(-), v = 0-10 for a(1)Δ(g), and v = 0-12 for b(1)Σ(g)(+). To the best of our knowledge, this is the first analysis that simultaneously fits spectra from all six O(2) isotopologues." @default.
• W305382246 created "2016-06-24" @default.
• W305382246 creator A5025259904 @default.
• W305382246 creator A5059653079 @default.
• W305382246 creator A5062389151 @default.
• W305382246 creator A5086402941 @default.
• W305382246 date "2012-07-10" @default.
• W305382246 modified "2023-10-02" @default.
• W305382246 title "High resolution spectral analysis of oxygen. I. Isotopically invariant Dunham fit for the $X^3 {rm Sigma }_g^ -$X3Σg−, <i>a</i>1Δ<i>g</i>, $b^1 {rm Sigma }_g^ +$b1Σg+ states" @default.
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