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• W3056687788 endingPage "7551" @default.
• W3056687788 startingPage "7544" @default.
• W3056687788 abstract "Solvent-free chemistry has been used to streamline synthesis, reduce waste, and access novel reactivity, but the physical nature of the reaction medium in the absence of solvent is often poorly understood. Here we reveal the phase behavior that enables the solvent-free carboxylation reaction in which carbonate, furan-2-carboxylate (furoate), and CO2 react to form furan-2,5-dicarboxylate (FDCA2-). This transformation has no solution-phase analogue and can be applied to convert lignocellulose into performance-advantaged plastics. Using operando powder X-ray diffraction and thermal analysis to elucidate the temperature- and conversion-dependent phase composition, we find that the reaction medium is a heterogeneous mixture of a ternary eutectic molten phase, solid Cs2CO3, and solid Cs2FDCA. During the reaction, the amounts of molten phase and solid Cs2CO3 diminish as solid Cs2FDCA accumulates. These insights are critical for increasing the scale of furoate carboxylation and provide a framework for guiding the development of other solvent-free transformations." @default.
• W3056687788 created "2020-08-24" @default.
• W3056687788 creator A5025223034 @default.
• W3056687788 creator A5070465273 @default.
• W3056687788 date "2020-08-19" @default.
• W3056687788 modified "2023-09-27" @default.
• W3056687788 title "Phase Behavior That Enables Solvent-Free Carbonate-Promoted Furoate Carboxylation" @default.
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• W3056687788 doi "https://doi.org/10.1021/acs.jpclett.0c02210" @default.
• W3056687788 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32812764" @default.
• W3056687788 hasPublicationYear "2020" @default.
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