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- W305961896 abstract "Abstract : A method of studying equilibria in refractory nitride systems at 1500-2800 K was developed. The equilibrium in the system NrN(x) - N2 was studied in the temperature range 2000-2800 K, the pressure range 0.1-300 mmHg, and a range of change in x from 0.7 to 1.0. The dependence of the equilibrium compositions on temperature and pressure was established. The composition ZrN is a special case. The decomposition equation used in the literature, ZrN yields Zr + 1/2 N2, was not corroborated at the pressures and temperatures investigated. As the composition of ZrN(x) changes, the heats and free energies of formation change considerably; this must be taken into account in thermodynamic calculations. As the composition changes from ZrN(0.56) to ZrN(1.0), the heats of formation change from 56,100 to 87,900 cal/mole. The conditions of formation of zirconium nitrides of given composition were studied, and a method of synthesizing them was developed. (Author)" @default.
- W305961896 created "2016-06-24" @default.
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- W305961896 date "1961-07-27" @default.
- W305961896 modified "2023-09-27" @default.
- W305961896 title "A STUDY OF EQUILIBRIUM IN A ZIRCONIUM-NITROGEN SYSTEM AT HIGH TEMPERATURES AND THE DEPENDENCE OF THE FREE ENERGY OF FORMATION OF ZRNX ON ITS COMPOSITION AND STRUCTURE" @default.
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