FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3068146615> ?p ?o ?g. }

• W3068146615 endingPage "1624" @default.
• W3068146615 startingPage "1624" @default.
• W3068146615 abstract "The metal–support interaction (MSI) has a remarkable effect on the catalytic properties, but how to precisely modulate its degree remains a huge challenge. Herein, polyvinylpyrrolidone (PVP) with three different molecular weights (MWs) (24, 58, and 130 kDa) was used as a capping agent to fabricate Ag nanoparticles (NPs) supported on ZrO2. The physiochemical properties of the catalysts were characterized by X-ray diffraction (XRD), Transmission Electron Microscope (TEM), X-ray Photoelectron Spectroscopy (XPS), and Fourier transform infrared (FT-IR) techniques. The impacts of MSI on the catalytic activity and reaction kinetics for aerobic oxidation of 5-hydroxymethylfurfural (HMF) were investigated. The results showed that the introduction of PVP with various MWs could efficiently tailor the interfacial interactions and charge transfers (CT) among PVP, the support, and Ag NPs, thereby affecting the oxidation activity of HMF. The turnover number (TON) for HMF oxidation decreases in the order of unsupported colloidal Ag clusters > Ag/ZrO2 (58,000) > Ag/ZrO2 (130,000) > Ag/ZrO2 (24,000) > Ag/ZrO2. The reason for this large difference in the catalytic activity for HMF oxidation is that various MWs of PVP result in a change of MSI, thereby facilitating CT from PVP to Ag metal sites. This study offers a new strategy for modulating MSI by varying the MW of capping agents, thereby tuning the catalytic properties in the oxidation of HMF." @default.
• W3068146615 created "2020-08-24" @default.
• W3068146615 creator A5006023014 @default.
• W3068146615 creator A5021029773 @default.
• W3068146615 creator A5038788588 @default.
• W3068146615 date "2020-08-19" @default.
• W3068146615 modified "2023-09-26" @default.
• W3068146615 title "Aerobic Oxidation of 5-Hydroxymethylfurfural over Ag Nanoparticle Catalysts Stabilized by Polyvinylpyrrolidone with Different Molecular Weights" @default.
• W3068146615 cites W1944207547 @default.
• W3068146615 cites W1997153376 @default.
• W3068146615 cites W2004517046 @default.
• W3068146615 cites W2017166072 @default.
• W3068146615 cites W2036347394 @default.
• W3068146615 cites W2037661249 @default.
• W3068146615 cites W2039170356 @default.
• W3068146615 cites W2060584746 @default.
• W3068146615 cites W2065750803 @default.
• W3068146615 cites W2078009702 @default.
• W3068146615 cites W2112054485 @default.
• W3068146615 cites W2193306869 @default.
• W3068146615 cites W2316003986 @default.
• W3068146615 cites W2324466894 @default.
• W3068146615 cites W2342348238 @default.
• W3068146615 cites W2472818174 @default.
• W3068146615 cites W2516192236 @default.
• W3068146615 cites W2523476675 @default.
• W3068146615 cites W2531884327 @default.
• W3068146615 cites W2544257833 @default.
• W3068146615 cites W2559882172 @default.
• W3068146615 cites W2569901556 @default.
• W3068146615 cites W2618879542 @default.
• W3068146615 cites W2749695511 @default.
• W3068146615 cites W2760072826 @default.
• W3068146615 cites W2763532339 @default.
• W3068146615 cites W2765468632 @default.
• W3068146615 cites W2770104093 @default.
• W3068146615 cites W2775136399 @default.
• W3068146615 cites W2786510483 @default.
• W3068146615 cites W2797266319 @default.
• W3068146615 cites W2804364614 @default.
• W3068146615 cites W2809018201 @default.
• W3068146615 cites W2810376782 @default.
• W3068146615 cites W2902752924 @default.
• W3068146615 cites W2914711837 @default.
• W3068146615 cites W2917506622 @default.
• W3068146615 cites W2924753393 @default.
• W3068146615 cites W2937809137 @default.
• W3068146615 cites W2963057673 @default.
• W3068146615 cites W2989413866 @default.
• W3068146615 doi "https://doi.org/10.3390/nano10091624" @default.
• W3068146615 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7558134" @default.
• W3068146615 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32825047" @default.
• W3068146615 hasPublicationYear "2020" @default.
• W3068146615 type Work @default.
• W3068146615 sameAs 3068146615 @default.
• W3068146615 citedByCount "6" @default.
• W3068146615 countsByYear W30681466152021 @default.
• W3068146615 countsByYear W30681466152022 @default.
• W3068146615 countsByYear W30681466152023 @default.
• W3068146615 crossrefType "journal-article" @default.
• W3068146615 hasAuthorship W3068146615A5006023014 @default.
• W3068146615 hasAuthorship W3068146615A5021029773 @default.
• W3068146615 hasAuthorship W3068146615A5038788588 @default.
• W3068146615 hasBestOaLocation W30681466151 @default.
• W3068146615 hasConcept C127413603 @default.
• W3068146615 hasConcept C13965031 @default.
• W3068146615 hasConcept C146088050 @default.
• W3068146615 hasConcept C155672457 @default.
• W3068146615 hasConcept C160892712 @default.
• W3068146615 hasConcept C161790260 @default.
• W3068146615 hasConcept C171250308 @default.
• W3068146615 hasConcept C175708663 @default.
• W3068146615 hasConcept C178790620 @default.
• W3068146615 hasConcept C185592680 @default.
• W3068146615 hasConcept C192562407 @default.
• W3068146615 hasConcept C2780077769 @default.
• W3068146615 hasConcept C2910317400 @default.
• W3068146615 hasConcept C42360764 @default.
• W3068146615 hasConcept C544153396 @default.
• W3068146615 hasConceptScore W3068146615C127413603 @default.
• W3068146615 hasConceptScore W3068146615C13965031 @default.
• W3068146615 hasConceptScore W3068146615C146088050 @default.
• W3068146615 hasConceptScore W3068146615C155672457 @default.
• W3068146615 hasConceptScore W3068146615C160892712 @default.
• W3068146615 hasConceptScore W3068146615C161790260 @default.
• W3068146615 hasConceptScore W3068146615C171250308 @default.
• W3068146615 hasConceptScore W3068146615C175708663 @default.
• W3068146615 hasConceptScore W3068146615C178790620 @default.
• W3068146615 hasConceptScore W3068146615C185592680 @default.
• W3068146615 hasConceptScore W3068146615C192562407 @default.
• W3068146615 hasConceptScore W3068146615C2780077769 @default.
• W3068146615 hasConceptScore W3068146615C2910317400 @default.
• W3068146615 hasConceptScore W3068146615C42360764 @default.
• W3068146615 hasConceptScore W3068146615C544153396 @default.
• W3068146615 hasIssue "9" @default.
• W3068146615 hasLocation W30681466151 @default.
• W3068146615 hasLocation W30681466152 @default.
• W3068146615 hasLocation W30681466153 @default.

• next