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- W307185837 abstract "The hydrated layered solids, hydrogen uranyl phosphate. HUO/sub 2/PO/sub 4/, HUP, and its isostructural neptunyl analog, HNpO/sub 2/PO/sub 4/, HNPP, can be intercalated with UO/sub 2/(2+) and NPO/sub 2/(2+) ions to yield a family of layered, hydrated solids that have been characterized by X-ray powder diffraction and by infrared, Raman, and electronic spectroscopy. Aqueous reactions of HUP with UO/sub 2/(2+) and of HNPP with NPO/sub 2/(2+) lead to hydrated layered solids, (UO/sub 2/)3(PO/sub 4/)/sub 2/, UP, and (NPO/sub 2/)/sub 3/(PO/sub 4/)/sub 2/, NPP; preparation of UP from HUP and of NPP from HNPP can also be effected by thermal decomposition of the parent solids, thus affording a set of self intercalation reactions that are reversible. Cross-intercalation reactions (UO/sub 2/(2+) into HNPP; NPO/sub 2/(2+) into HUP) also proceed under stoichiometric conditions." @default.
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- W307185837 date "1989-05-17" @default.
- W307185837 modified "2023-09-24" @default.
- W307185837 title "Intercalation reactions of the neptunyl(vi) dication with hydrogen uranyl phosphate and hydrogen neptunyl phosphate host lattices. Technical report" @default.
- W307185837 hasPublicationYear "1989" @default.
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