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- W3075119080 abstract "The N -heterocyclic carbene (NHC)-catalyzed reactions via radicals open new opportunities for transformation of aldehydes beyond classical two electron pathways. The N -heterocyclic carbene (NHC)-catalyzed reactions involving two-electron reaction pathway have been well-established. However, the development of NHC-catalyzed radical reactions is still in its infancy in terms of reaction types and enantioselectivity. In the past decade, several elegant NHC-catalyzed radical reactions have been developed, including NHC-catalyzed oxidation of aldehydes to esters, reductive coupling reactions using Breslow intermediate as SET reductant and NHC-catalyzed reactions via radical homoenolates, dienoaltes and trienolates. This review summarizes the recent advances in NHC-catalyzed reactions involving radical intermediates." @default.
- W3075119080 created "2020-08-24" @default.
- W3075119080 creator A5056222697 @default.
- W3075119080 creator A5078690639 @default.
- W3075119080 date "2021-02-01" @default.
- W3075119080 modified "2023-10-17" @default.
- W3075119080 title "Recent advances in N-heterocyclic carbene-catalyzed radical reactions" @default.
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- W3075119080 doi "https://doi.org/10.1016/j.cclet.2020.08.027" @default.
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