Matches in SemOpenAlex for { <https://semopenalex.org/work/W3075563446> ?p ?o ?g. }
- W3075563446 endingPage "7428" @default.
- W3075563446 startingPage "7423" @default.
- W3075563446 abstract "Chemical reactions in aqueous microdroplets often exhibit unusual kinetic and thermodynamic properties not observed in bulk solution. While an electric field has been implicated at the water interface, there has been no direct measurement in aqueous microdroplets, largely due to the lack of proper measurement tools. Herein, we employ newly developed stimulated Raman excited fluorescence microscopy to measure the electric field at the water–oil interface of microdroplets. As determined by the vibrational Stark effect of a nitrile-bearing fluorescent probe, the strength of the electric field is found to be on the order of 107 V/cm. This strong electric field aligns probe dipoles with respect to the interface. The formation of the electric field likely arises from charge separation caused by the adsorption of negative ions at the water–oil interface of microdroplets. We suggest that this strong electric field might account in part for the unique properties of chemical reactions reported in microdroplets." @default.
- W3075563446 created "2020-08-24" @default.
- W3075563446 creator A5021362318 @default.
- W3075563446 creator A5048649695 @default.
- W3075563446 creator A5081170581 @default.
- W3075563446 creator A5083063825 @default.
- W3075563446 date "2020-08-17" @default.
- W3075563446 modified "2023-10-09" @default.
- W3075563446 title "Strong Electric Field Observed at the Interface of Aqueous Microdroplets" @default.
- W3075563446 cites W1934555031 @default.
- W3075563446 cites W1974730206 @default.
- W3075563446 cites W1976793490 @default.
- W3075563446 cites W1989003164 @default.
- W3075563446 cites W2000815209 @default.
- W3075563446 cites W2008615905 @default.
- W3075563446 cites W2011074581 @default.
- W3075563446 cites W2013107255 @default.
- W3075563446 cites W2040701913 @default.
- W3075563446 cites W2044367357 @default.
- W3075563446 cites W2049745495 @default.
- W3075563446 cites W2064719117 @default.
- W3075563446 cites W2067639646 @default.
- W3075563446 cites W2068522177 @default.
- W3075563446 cites W2077421481 @default.
- W3075563446 cites W2099086165 @default.
- W3075563446 cites W2120298192 @default.
- W3075563446 cites W2128625777 @default.
- W3075563446 cites W2129262771 @default.
- W3075563446 cites W2132797653 @default.
- W3075563446 cites W2137890896 @default.
- W3075563446 cites W2138098178 @default.
- W3075563446 cites W2149411464 @default.
- W3075563446 cites W2170317460 @default.
- W3075563446 cites W2292472768 @default.
- W3075563446 cites W2324891522 @default.
- W3075563446 cites W2333873148 @default.
- W3075563446 cites W2403412395 @default.
- W3075563446 cites W2435408353 @default.
- W3075563446 cites W2585051437 @default.
- W3075563446 cites W2612535150 @default.
- W3075563446 cites W2758302597 @default.
- W3075563446 cites W2765239306 @default.
- W3075563446 cites W2776846038 @default.
- W3075563446 cites W2802300363 @default.
- W3075563446 cites W2803477316 @default.
- W3075563446 cites W2813373686 @default.
- W3075563446 cites W2884196243 @default.
- W3075563446 cites W2892556061 @default.
- W3075563446 cites W2934363961 @default.
- W3075563446 cites W2934792782 @default.
- W3075563446 cites W2940682130 @default.
- W3075563446 cites W2951015771 @default.
- W3075563446 cites W2951587835 @default.
- W3075563446 cites W2953060425 @default.
- W3075563446 cites W2963596279 @default.
- W3075563446 cites W2969629202 @default.
- W3075563446 cites W2971299686 @default.
- W3075563446 cites W2981107116 @default.
- W3075563446 cites W2988331759 @default.
- W3075563446 cites W3006793855 @default.
- W3075563446 cites W3017097444 @default.
- W3075563446 cites W3023568869 @default.
- W3075563446 cites W3048303340 @default.
- W3075563446 cites W4244818255 @default.
- W3075563446 doi "https://doi.org/10.1021/acs.jpclett.0c02061" @default.
- W3075563446 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32804510" @default.
- W3075563446 hasPublicationYear "2020" @default.
- W3075563446 type Work @default.
- W3075563446 sameAs 3075563446 @default.
- W3075563446 citedByCount "124" @default.
- W3075563446 countsByYear W30755634462020 @default.
- W3075563446 countsByYear W30755634462021 @default.
- W3075563446 countsByYear W30755634462022 @default.
- W3075563446 countsByYear W30755634462023 @default.
- W3075563446 crossrefType "journal-article" @default.
- W3075563446 hasAuthorship W3075563446A5021362318 @default.
- W3075563446 hasAuthorship W3075563446A5048649695 @default.
- W3075563446 hasAuthorship W3075563446A5081170581 @default.
- W3075563446 hasAuthorship W3075563446A5083063825 @default.
- W3075563446 hasConcept C113196181 @default.
- W3075563446 hasConcept C121332964 @default.
- W3075563446 hasConcept C147789679 @default.
- W3075563446 hasConcept C159467904 @default.
- W3075563446 hasConcept C173523689 @default.
- W3075563446 hasConcept C178790620 @default.
- W3075563446 hasConcept C184651966 @default.
- W3075563446 hasConcept C185592680 @default.
- W3075563446 hasConcept C202444582 @default.
- W3075563446 hasConcept C33923547 @default.
- W3075563446 hasConcept C43617362 @default.
- W3075563446 hasConcept C60799052 @default.
- W3075563446 hasConcept C62520636 @default.
- W3075563446 hasConcept C9652623 @default.
- W3075563446 hasConceptScore W3075563446C113196181 @default.
- W3075563446 hasConceptScore W3075563446C121332964 @default.
- W3075563446 hasConceptScore W3075563446C147789679 @default.
- W3075563446 hasConceptScore W3075563446C159467904 @default.
- W3075563446 hasConceptScore W3075563446C173523689 @default.