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- W3080213583 abstract "Reported herein is a unified strategy to generate difluoroalkyl radicals from readily prepared α-difluorinated gem-diols by single electron oxidation. Under microwave irradiation, a catalytic amount of oxidant Cu(OAc)2 succeeds in the formation of transient difluoroalkyl radicals in situ, for the first time. The reaction features a simple protocol, short reaction time, scalability, and high yield. The synthetic utility of this new methodology was also explored for the synthesis of difluoroalkylated spiro-cyclohexadienones, which is an important core structure in natural products and pharmaceuticals." @default.
- W3080213583 created "2020-09-01" @default.
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- W3080213583 date "2020-08-27" @default.
- W3080213583 modified "2023-10-15" @default.
- W3080213583 title "Microwave-Assisted Copper Catalysis of α-Difluorinated <i>gem</i>-Diol toward Difluoroalkyl Radical for Hydrodifluoroalkylation of <i>para</i>-Quinone Methides" @default.
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- W3080213583 doi "https://doi.org/10.1021/acs.joc.0c01686" @default.
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