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- W3080245763 endingPage "121688" @default.
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- W3080245763 abstract "Abstract A novel Zn-based porous MOF, namely, [Zn2.5(dcpp)(ad)(HCOO)·3H2O·3DMF]n (1) featuring rare 1D channels with capsule-shaped inner cavities, has been successfully constructed from mixed 2,6-di(2′,5′-dicarboxylphenyl)pyridine and adenine organic linkers. The adsorption properties of 1 with respect to CO2, C2H2 and CH4 were systematically investigated. Taking advantage of synergetic effect of the high density of Lewis basic sites and open O donor sites, the activated 1′ possesses considerable uptake capacity for CO2 (106.3 and 59.2 cm3 g−1 under 1 bar at 273 and 298 K, STP) and C2H2 (136.3 and 101.8 cm3 g−1 under 1 bar at 273 and 298 K, STP), as well as high CO2/CH4 and C2H2/CH4 selectivities (4.4 and 16.2) at ambient temperature." @default.
- W3080245763 created "2020-09-01" @default.
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- W3080245763 date "2020-12-01" @default.
- W3080245763 modified "2023-10-13" @default.
- W3080245763 title "A novel microporous metal–organic framework with Lewis basic sites and open O donor sites: Crystal structure and adsorption properties" @default.
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- W3080245763 doi "https://doi.org/10.1016/j.jssc.2020.121688" @default.
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