FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3080270788> ?p ?o ?g. }

• W3080270788 endingPage "1885" @default.
• W3080270788 startingPage "1885" @default.
• W3080270788 abstract "In the present work it was shown that low lattice energy ammonium salts are not favorable for polymer electrolyte preparation for electrochemical device applications. Polymer blend electrolytes based on chitosan:poly(ethylene oxide) (CS:PEO) incorporated with various amounts of low lattice energy NH4BF4ammonium salt have been prepared using the solution cast technique. Both structural and morphological studies were carried out to understand the phenomenon of ion association. Sharp peaks appeared in X-ray diffraction (XRD) spectra of the samples with high salt concentration. The degree of crystallinity increased from 8.52 to 65.84 as the salt concentration increased up to 40 wt.%. These are correlated to the leakage of the associated anions and cations of the salt to the surface of the polymer. The structural behaviors were further confirmed by morphological study. The morphological results revealed the large-sized protruded salts at high salt concentration. Based on lattice energy of salts, the phenomena of salt leakage were interpreted. Ammonium salts with lattice energy lower than 600 kJ/mol are not preferred for polymer electrolyte preparation due to the significant tendency of ion association among cations and anions. Electrical impedance spectroscopy was used to estimate the conductivity of the samples. It was found that the bulk resistance increased from 1.1 × 104 ohm to 0.7 × 105 ohm when the salt concentration raised from 20 wt.% to 40 wt.%, respectively; due to the association of cations and anions. The low value of direct current (DC) conductivity (7.93 × 10−7 S/cm) addressed the non-suitability of the electrolytes for electrochemical device applications. The calculated values of the capacitance over the interfaces of electrodes-electrolytes (C2) were found to drop from 1.32 × 10−6 F to 3.13 × 10−7 F with increasing salt concentration. The large values of dielectric constant at low frequencies are correlated to the electrode polarization phenomena while their decrements with rising frequency are attributed to the lag of ion polarization in respect of the fast orientation of the applied alternating current (AC) field. The imaginary part of the electric modulus shows obvious peaks known as conduction relaxation peaks." @default.
• W3080270788 created "2020-09-01" @default.
• W3080270788 creator A5025502555 @default.
• W3080270788 creator A5034710991 @default.
• W3080270788 creator A5036799501 @default.
• W3080270788 creator A5036890018 @default.
• W3080270788 creator A5039031424 @default.
• W3080270788 creator A5048199625 @default.
• W3080270788 creator A5057414689 @default.
• W3080270788 creator A5080584190 @default.
• W3080270788 creator A5081018866 @default.
• W3080270788 date "2020-08-21" @default.
• W3080270788 modified "2023-10-16" @default.
• W3080270788 title "Drawbacks of Low Lattice Energy Ammonium Salts for Ion-Conducting Polymer Electrolyte Preparation: Structural, Morphological and Electrical Characteristics of CS:PEO:NH4BF4-Based Polymer Blend Electrolytes" @default.
• W3080270788 cites W1781534030 @default.
• W3080270788 cites W1963840938 @default.
• W3080270788 cites W1966668497 @default.
• W3080270788 cites W1972210181 @default.
• W3080270788 cites W1976252757 @default.
• W3080270788 cites W1979746799 @default.
• W3080270788 cites W1984396621 @default.
• W3080270788 cites W1987686483 @default.
• W3080270788 cites W1991164248 @default.
• W3080270788 cites W1996320346 @default.
• W3080270788 cites W2000730633 @default.
• W3080270788 cites W2003123571 @default.
• W3080270788 cites W2003701418 @default.
• W3080270788 cites W2004210286 @default.
• W3080270788 cites W2005960082 @default.
• W3080270788 cites W2010644029 @default.
• W3080270788 cites W2013477175 @default.
• W3080270788 cites W2013555861 @default.
• W3080270788 cites W2016943764 @default.
• W3080270788 cites W2019858202 @default.
• W3080270788 cites W2031440131 @default.
• W3080270788 cites W2032493592 @default.
• W3080270788 cites W2033985788 @default.
• W3080270788 cites W2039071366 @default.
• W3080270788 cites W2045092846 @default.
• W3080270788 cites W2047758147 @default.
• W3080270788 cites W2049686423 @default.
• W3080270788 cites W2050951419 @default.
• W3080270788 cites W2051707485 @default.
• W3080270788 cites W2055810687 @default.
• W3080270788 cites W2056490686 @default.
• W3080270788 cites W2059017762 @default.
• W3080270788 cites W2069402356 @default.
• W3080270788 cites W2069610755 @default.
• W3080270788 cites W2076668960 @default.
• W3080270788 cites W2086139019 @default.
• W3080270788 cites W2089700014 @default.
• W3080270788 cites W2090937286 @default.
• W3080270788 cites W2092227202 @default.
• W3080270788 cites W2096478079 @default.
• W3080270788 cites W2106885274 @default.
• W3080270788 cites W2111012968 @default.
• W3080270788 cites W2122953039 @default.
• W3080270788 cites W2126795505 @default.
• W3080270788 cites W2129625708 @default.
• W3080270788 cites W2139557344 @default.
• W3080270788 cites W2158197941 @default.
• W3080270788 cites W2177519571 @default.
• W3080270788 cites W2317251887 @default.
• W3080270788 cites W2345092977 @default.
• W3080270788 cites W2404826623 @default.
• W3080270788 cites W2473340751 @default.
• W3080270788 cites W2531748000 @default.
• W3080270788 cites W2555931254 @default.
• W3080270788 cites W2617274632 @default.
• W3080270788 cites W2744056418 @default.
• W3080270788 cites W2772606881 @default.
• W3080270788 cites W2773255197 @default.
• W3080270788 cites W2790599553 @default.
• W3080270788 cites W2790928926 @default.
• W3080270788 cites W2791609601 @default.
• W3080270788 cites W2801683359 @default.
• W3080270788 cites W2803100028 @default.
• W3080270788 cites W2886675565 @default.
• W3080270788 cites W2888967732 @default.
• W3080270788 cites W2890794167 @default.
• W3080270788 cites W2895975758 @default.
• W3080270788 cites W2898237915 @default.
• W3080270788 cites W2901344390 @default.
• W3080270788 cites W2912526489 @default.
• W3080270788 cites W2921121717 @default.
• W3080270788 cites W2924849831 @default.
• W3080270788 cites W2943984836 @default.
• W3080270788 cites W2944468174 @default.
• W3080270788 cites W2956470195 @default.
• W3080270788 cites W2960627699 @default.
• W3080270788 cites W2969867656 @default.
• W3080270788 cites W2972369262 @default.
• W3080270788 cites W2974120690 @default.
• W3080270788 cites W2981207383 @default.
• W3080270788 cites W2981887273 @default.
• W3080270788 cites W2985108501 @default.
• W3080270788 cites W2989826084 @default.
• W3080270788 cites W2995242239 @default.

• next