Matches in SemOpenAlex for { <https://semopenalex.org/work/W3080450033> ?p ?o ?g. }
- W3080450033 endingPage "9907" @default.
- W3080450033 startingPage "9900" @default.
- W3080450033 abstract "Two-coordinate Cu(I) and Au(I) complexes supported by bicyclic (alkyl)(amino)carbene, [BICAAC-CuCl] (1), [BICAAC-CuI] (2), [(BICAAC)2Cu]+[PF6]– (3) and [(BICAAC)2Au]+[AuCl2]– (6) have been synthesized. The reaction of cyclic (alkyl)(amino)carbene, CAACcy with CuCl afforded [CAACcy-CuCl] (4) and its further reaction with KPF6 gave [(CAACcy)2Cu]+[PF6]– (5). Complexes 1–6 have been characterized by multinuclear NMR, IR and UV-Vis., spectroscopic method and high-resolution mass spectrometry (HRMS). Single crystal X-ray structure of heteroleptic complexes 1 and 4 and homoleptic complexes [(BICAAC)2Cu]+[CuI2]– (2’), 3 and 6 have also been determined. The crystal structure of these complexes confirmed linear two-coordinate geometry around the metal centers. In the solid- state, complexes 1, 2’, 4 and 6 displayed C−H⋯M (M=Cu, Au) and weak non-covalent C−H⋯X (X=Cl, I) and C−H⋯H−C interactions. Computational calculations correlate well to the experimentally observed geometry and help elucidate the absorption characteristics type of transitions and the frontier orbitals involved in them." @default.
- W3080450033 created "2020-09-01" @default.
- W3080450033 creator A5005234403 @default.
- W3080450033 creator A5008650576 @default.
- W3080450033 creator A5012783857 @default.
- W3080450033 creator A5017690668 @default.
- W3080450033 creator A5049580661 @default.
- W3080450033 creator A5058674399 @default.
- W3080450033 creator A5072343415 @default.
- W3080450033 date "2020-08-24" @default.
- W3080450033 modified "2023-10-01" @default.
- W3080450033 title "Two‐Coordinate Cu(I) and Au(I) Complexes Supported by BICAAC and CAAC Ligands" @default.
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