FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3080526052> ?p ?o ?g. }

• W3080526052 endingPage "21287" @default.
• W3080526052 startingPage "21275" @default.
• W3080526052 abstract "The response of the electronic properties of the HfN2 monolayer to external perturbation, such as strain and electric fields, has been extensively investigated using density functional theory calculations for its device-based applications and photocatalysis. The HfN2 monolayer is found to be a semiconductor showing a direct band gap of 1.44 eV, which is widely tunable by 0.9 eV via application of biaxial strain. Furthermore, the tunability in the band edges of the HfN2 monolayer straddling the water redox potential under a biaxial strain of ±10% makes it suitable for solar energy harvesting via photocatalytic applications over a wide range (0-7) of pH. The band gap can be decreased by 29.8% under a biaxial tensile strain of 10%. Upon incorporation of spin orbit coupling (SOC) a large spin splitting at the conduction band (Δc ∼ 314 meV) and a small splitting at the valence band (Δv ∼ 32 meV) are noted, which is attributable to the orbital composition of the band edges. The spin splitting in the band edges is found to be adjustable via biaxial compressive strain. The strain dependent mechanical properties and stability reveal the ability of the HfN2 monolayer to withstand a large magnitude of strain of up to ±10%, thereby bringing about a giant tunability in its Young modulus (Y) from 66 N m-1 to 283 N m-1, which is gainfully exploitable in flexible electronics. The tunability in Y over such a wide range has not been observed in other 2D materials. Moreover, the HfN2 monolayer undergoes a transition from a semiconducting to a metallic state under the application of a normal electric field or gate voltage of 0.48 V Å-1, which may potentially serve as the OFF (semiconducting) and ON (metallic) state in devices. Interestingly, an electric field of such intensity has been realized experimentally using pulsed ac field technology. Such a small gate voltage will greatly lower its power consumption. The electronic origin of this transition from the OFF to the ON state is found to arise from unoccupied NFEG (Nearly Free Electron Gas) states. A HfN2 monolayer based tunnel field effect transistor (t-FET) is proposed herewith as a model device for low-power digital data storage, thereby paving new avenues in flexible electronics and memory devices." @default.
• W3080526052 created "2020-09-01" @default.
• W3080526052 creator A5016882650 @default.
• W3080526052 creator A5052092090 @default.
• W3080526052 creator A5062232295 @default.
• W3080526052 date "2020-01-01" @default.
• W3080526052 modified "2023-09-30" @default.
• W3080526052 title "Exceptional mechano-electronic properties in the HfN₂ monolayer: a promising candidate in low-power flexible electronics, memory devices and photocatalysis" @default.
• W3080526052 cites W1596330784 @default.
• W3080526052 cites W1893431947 @default.
• W3080526052 cites W1950367212 @default.
• W3080526052 cites W1970127494 @default.
• W3080526052 cites W1981368803 @default.
• W3080526052 cites W1994880295 @default.
• W3080526052 cites W2006839785 @default.
• W3080526052 cites W2007395042 @default.
• W3080526052 cites W2010971702 @default.
• W3080526052 cites W2022405597 @default.
• W3080526052 cites W2025725517 @default.
• W3080526052 cites W2034932701 @default.
• W3080526052 cites W2058122340 @default.
• W3080526052 cites W2060496338 @default.
• W3080526052 cites W2067983335 @default.
• W3080526052 cites W2069625343 @default.
• W3080526052 cites W2078118572 @default.
• W3080526052 cites W2079689884 @default.
• W3080526052 cites W2080787145 @default.
• W3080526052 cites W2083222334 @default.
• W3080526052 cites W2087032948 @default.
• W3080526052 cites W2092157292 @default.
• W3080526052 cites W2096453913 @default.
• W3080526052 cites W2151800339 @default.
• W3080526052 cites W2154044591 @default.
• W3080526052 cites W2184640106 @default.
• W3080526052 cites W2332278225 @default.
• W3080526052 cites W2334012917 @default.
• W3080526052 cites W2334135567 @default.
• W3080526052 cites W2343240592 @default.
• W3080526052 cites W2416108250 @default.
• W3080526052 cites W2475331696 @default.
• W3080526052 cites W2554136829 @default.
• W3080526052 cites W2592457753 @default.
• W3080526052 cites W2593478887 @default.
• W3080526052 cites W2604248054 @default.
• W3080526052 cites W2610765787 @default.
• W3080526052 cites W2616701515 @default.
• W3080526052 cites W2620851704 @default.
• W3080526052 cites W2743239867 @default.
• W3080526052 cites W2748147434 @default.
• W3080526052 cites W2749715355 @default.
• W3080526052 cites W2767504722 @default.
• W3080526052 cites W2787538226 @default.
• W3080526052 cites W2791030513 @default.
• W3080526052 cites W2795060021 @default.
• W3080526052 cites W2810326414 @default.
• W3080526052 cites W2884009761 @default.
• W3080526052 cites W2886080302 @default.
• W3080526052 cites W2889704558 @default.
• W3080526052 cites W2890548934 @default.
• W3080526052 cites W2896343566 @default.
• W3080526052 cites W2898697192 @default.
• W3080526052 cites W2900741327 @default.
• W3080526052 cites W2901990501 @default.
• W3080526052 cites W2902416803 @default.
• W3080526052 cites W2909240409 @default.
• W3080526052 cites W2911503582 @default.
• W3080526052 cites W2921465408 @default.
• W3080526052 cites W2928678977 @default.
• W3080526052 cites W2938569389 @default.
• W3080526052 cites W2951729744 @default.
• W3080526052 cites W2958133695 @default.
• W3080526052 cites W2960504072 @default.
• W3080526052 cites W2962884620 @default.
• W3080526052 cites W2963288984 @default.
• W3080526052 cites W2965009920 @default.
• W3080526052 cites W2968551496 @default.
• W3080526052 cites W2969875837 @default.
• W3080526052 cites W2980477232 @default.
• W3080526052 cites W2981794520 @default.
• W3080526052 cites W2982008605 @default.
• W3080526052 cites W2991660994 @default.
• W3080526052 cites W2991838973 @default.
• W3080526052 cites W2995466395 @default.
• W3080526052 cites W2995968297 @default.
• W3080526052 cites W2996494390 @default.
• W3080526052 cites W2998887553 @default.
• W3080526052 cites W2999669732 @default.
• W3080526052 cites W2999865922 @default.
• W3080526052 cites W3002256979 @default.
• W3080526052 cites W3006122664 @default.
• W3080526052 cites W3013467425 @default.
• W3080526052 cites W3015573866 @default.
• W3080526052 cites W3030911889 @default.
• W3080526052 cites W3034374808 @default.
• W3080526052 cites W3049478088 @default.
• W3080526052 cites W3084131387 @default.
• W3080526052 cites W3101841684 @default.
• W3080526052 cites W3124637862 @default.

• next