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- W3080651299 abstract "Titanium oxide clusters (TOCs) have been emerging as a new type of inorganic molecular entities of supramolecular chemistry. Herein, a perspective on the structures and functionalities of TOCs over the past three decades is given and the paramount roles of TOCs in serving supramolecular chemistry are demonstrated. Four types of supramolecular assemblies based on TOCs are reviewed, namely, TOC hosts for ion inclusion, mechanically interlocked molecular systems built from cyclic TOCs, reactivities of surface sites toward ligand exchange, and hierarchical structures of TOCs. The principles and advantages of TOCs toward each application are fully discussed, along with structural analyses. Following this path, more functional TOC-based supramolecular systems may be designed and synthesized in the future, which, in turn, will certainly enhance research into both supramolecular and coordination chemistry of titanium." @default.
- W3080651299 created "2020-09-01" @default.
- W3080651299 creator A5010294985 @default.
- W3080651299 creator A5085596479 @default.
- W3080651299 date "2021-01-14" @default.
- W3080651299 modified "2023-09-27" @default.
- W3080651299 title "Supramolecular Chemistry of Titanium Oxide Clusters" @default.
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- W3080651299 doi "https://doi.org/10.1002/chem.202003378" @default.
- W3080651299 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32964513" @default.
- W3080651299 hasPublicationYear "2021" @default.
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