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- W3080655413 abstract "Abstract Macromolecules have a strong tendency to interact with each other in solution to form a supramolecular structure through various secondary binding forces. In this study, nucleobase‐containing templates poly(9‐(4‐vinylbenzyl)adenine) (P S AH) and poly(1‐(4‐vinylbenzyl)cytosine) (P S CH) are prepared by reversible addition‐fragmentation chain transfer (RAFT) polymerization. Vinylbenzyl thymine (M S T) is polymerized in the presence of these two nucleobase‐containing templates. M S T shows higher affinities toward the template P S AH compared with the template P S CH. In accordance with the Watson–Crick pairing principle, thymine forms hydrogen bonding (H‐bonding) with adenine, but not between thymine and cytosine. A complex is formed when P S AH is used as template which indicates that there is a template polymerization of nucleobase complexes via molecular recognition." @default.
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- W3080655413 date "2020-08-23" @default.
- W3080655413 modified "2023-09-29" @default.
- W3080655413 title "Templated Polymerization of Nucleobase Complexes via Molecular Recognition" @default.
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- W3080655413 doi "https://doi.org/10.1002/marc.202000352" @default.
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