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- W3080980422 abstract "Herein, ethylenediamine functionalized porous carbon (PC-ED/1.5) was synthesized, then characterized by various methods and finally used as a functional material for Cu(ii) and Pb(ii) ion removal from water. XPS revealed the presence of numerous functionalities within the surface of PC including -NH and C-N-C groups. Furthermore, SBET, RS, XRD and FTIR analyses confirmed the changes implemented on the PC surface. Thereafter, a systematic study was implemented to analyze the interactions of the PC-ED/1.5 surface with Cu(ii) and Pb(ii) heavy metal ions. Hence, adsorption experiments showed that the PC-ED/1.5 exhibits maximum adsorption capacities of 123.45 mg g-1 and 140.84 mg g-1 for Cu(ii) and Pb(ii), respectively. Moreover, in situ electrostatic interactions occurring between the divalent cation and the PC-ED/1.5 functional groups was investigated. The mechanism involves chelation processes, electrostatic interactions and mechanical trapping of the metal ions in the adsorbent pores. Interestingly, a synergistic effect of the pores and surface active sites was observed. Finally, by using alginate bio-polymer we prepared membrane films of PC-ED/1.5 which showed long-term stability, regeneration capabilities and high mass recovery." @default.
- W3080980422 created "2020-09-01" @default.
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- W3080980422 date "2020-01-01" @default.
- W3080980422 modified "2023-09-25" @default.
- W3080980422 title "New amino group functionalized porous carbon for strong chelation ability towards toxic heavy metals" @default.
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- W3080980422 doi "https://doi.org/10.1039/d0ra05220e" @default.
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