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• W3081017640 endingPage "11929" @default.
• W3081017640 startingPage "11925" @default.
• W3081017640 abstract "A rare 3D porous inorganic–organic polyoxoniobate framework based on the cubic polyoxoniobate-cupric-complex cage {[Cu(en)2]@{[Cu2(en)2(trz)2]6(Nb68O188)}} (1a), has been successfully synthesized by a hydrothermal method. The cubic cages 1a are connected with 4-(tetrazol-5-yl)pyridine to form a 1D pillar-like chain structure, and every 1D pillar-like chain is further linked with four adjacent pillar-like chains by the [Cu(en)2]2+ complex to form a 3D porous inorganic–organic polyoxoniobate framework with 4-connected CdSO4-type topology. To our knowledge, it is the first time that three different types of organic ligands are simultaneously introduced into one polyoxoniobate. This material also exhibits a high vapor adsorption capacity and good ionic conductivity properties." @default.
• W3081017640 created "2020-09-01" @default.
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• W3081017640 date "2020-08-27" @default.
• W3081017640 modified "2023-10-16" @default.
• W3081017640 title "A Rare 3D Porous Inorganic–Organic Hybrid Polyoxometalate Framework Based on a Cubic Polyoxoniobate-Cupric-Complex Cage with a High Water Vapor Adsorption Capacity" @default.
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• W3081017640 doi "https://doi.org/10.1021/acs.inorgchem.0c01826" @default.
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