Matches in SemOpenAlex for { <https://semopenalex.org/work/W3081094544> ?p ?o ?g. }
- W3081094544 endingPage "108208" @default.
- W3081094544 startingPage "108208" @default.
- W3081094544 abstract "Abstract A novel tetranuclear copper(II) complex, [Cu(H2O)5][Cu4(cpdp)2(adip)]ClBr∙2CH3OH·8H2O (1) of carboxylate-based symmetrical multidentate ligand, H3cpdp [H3cpdp = N,N'-Bis[2-carboxybenzomethyl]-N,N'-Bis[2-pyridylmethyl]-1,3-diaminopropan-2-ol; adip = adipate], has been synthesized and fully characterized. Complex 1 has been synthesized by carrying out reaction of ligand H3cpdp with stoichiometric amounts of CuCl2·2H2O/Na2(CH2CH2COO)2 in methanol-water in the presence of NaOH at room temperature. The solid state structure of 1 consists of a [Cu4(µ4-adip)] core unit which is held together by two multidentate bridging ligands, cpdp3−. In fact, complex 1 can be viewed as a “dimer-of-dimers” generated by self-assembly of two [Cu2(cpdp)]+ units exclusively bridged by one adipate group in a μ4:η1:η1:η1:η1 fashion. Variable-temperature (2–300 K) magnetic susceptibility measurements disclose the presence of antiferromagnetic interactions among the copper(II) ions. Thermal behaviour of 1 has been investigated by thermogravimetric analysis specifying that the complex is stable up to ∼200 °C." @default.
- W3081094544 created "2020-09-01" @default.
- W3081094544 creator A5028426081 @default.
- W3081094544 creator A5036948580 @default.
- W3081094544 creator A5050561740 @default.
- W3081094544 creator A5054296042 @default.
- W3081094544 creator A5078534604 @default.
- W3081094544 creator A5088625276 @default.
- W3081094544 date "2020-11-01" @default.
- W3081094544 modified "2023-10-17" @default.
- W3081094544 title "Synthesis, structure and properties of a novel self-assembled tetranuclear copper(II) complex derived from carboxylate-based multidentate ligand" @default.
- W3081094544 cites W1151490709 @default.
- W3081094544 cites W1911784743 @default.
- W3081094544 cites W1965612466 @default.
- W3081094544 cites W1973077202 @default.
- W3081094544 cites W1974200626 @default.
- W3081094544 cites W1985549311 @default.
- W3081094544 cites W1986315495 @default.
- W3081094544 cites W1999151173 @default.
- W3081094544 cites W1999880906 @default.
- W3081094544 cites W2002845466 @default.
- W3081094544 cites W2003023778 @default.
- W3081094544 cites W2036564578 @default.
- W3081094544 cites W2041854369 @default.
- W3081094544 cites W2054571981 @default.
- W3081094544 cites W2060520410 @default.
- W3081094544 cites W2074889057 @default.
- W3081094544 cites W2079103792 @default.
- W3081094544 cites W2098899618 @default.
- W3081094544 cites W2104543617 @default.
- W3081094544 cites W2105249240 @default.
- W3081094544 cites W2121843293 @default.
- W3081094544 cites W2125470685 @default.
- W3081094544 cites W2129612320 @default.
- W3081094544 cites W2150264392 @default.
- W3081094544 cites W2317140353 @default.
- W3081094544 cites W2341069136 @default.
- W3081094544 cites W2530434733 @default.
- W3081094544 cites W2565310970 @default.
- W3081094544 cites W2606736732 @default.
- W3081094544 cites W2607347271 @default.
- W3081094544 cites W2623707311 @default.
- W3081094544 cites W2739254470 @default.
- W3081094544 cites W2769880714 @default.
- W3081094544 cites W2800011085 @default.
- W3081094544 cites W2804152776 @default.
- W3081094544 cites W2888479710 @default.
- W3081094544 cites W2909724276 @default.
- W3081094544 cites W2924812918 @default.
- W3081094544 cites W2952993688 @default.
- W3081094544 cites W3001558171 @default.
- W3081094544 cites W3012190331 @default.
- W3081094544 cites W3014961705 @default.
- W3081094544 cites W3033678142 @default.
- W3081094544 cites W394911817 @default.
- W3081094544 doi "https://doi.org/10.1016/j.inoche.2020.108208" @default.
- W3081094544 hasPublicationYear "2020" @default.
- W3081094544 type Work @default.
- W3081094544 sameAs 3081094544 @default.
- W3081094544 citedByCount "4" @default.
- W3081094544 countsByYear W30810945442021 @default.
- W3081094544 countsByYear W30810945442022 @default.
- W3081094544 crossrefType "journal-article" @default.
- W3081094544 hasAuthorship W3081094544A5028426081 @default.
- W3081094544 hasAuthorship W3081094544A5036948580 @default.
- W3081094544 hasAuthorship W3081094544A5050561740 @default.
- W3081094544 hasAuthorship W3081094544A5054296042 @default.
- W3081094544 hasAuthorship W3081094544A5078534604 @default.
- W3081094544 hasAuthorship W3081094544A5088625276 @default.
- W3081094544 hasConcept C115624301 @default.
- W3081094544 hasConcept C116569031 @default.
- W3081094544 hasConcept C170493617 @default.
- W3081094544 hasConcept C178516000 @default.
- W3081094544 hasConcept C178790620 @default.
- W3081094544 hasConcept C185592680 @default.
- W3081094544 hasConcept C2778074193 @default.
- W3081094544 hasConcept C544778455 @default.
- W3081094544 hasConcept C55493867 @default.
- W3081094544 hasConcept C71240020 @default.
- W3081094544 hasConcept C8010536 @default.
- W3081094544 hasConceptScore W3081094544C115624301 @default.
- W3081094544 hasConceptScore W3081094544C116569031 @default.
- W3081094544 hasConceptScore W3081094544C170493617 @default.
- W3081094544 hasConceptScore W3081094544C178516000 @default.
- W3081094544 hasConceptScore W3081094544C178790620 @default.
- W3081094544 hasConceptScore W3081094544C185592680 @default.
- W3081094544 hasConceptScore W3081094544C2778074193 @default.
- W3081094544 hasConceptScore W3081094544C544778455 @default.
- W3081094544 hasConceptScore W3081094544C55493867 @default.
- W3081094544 hasConceptScore W3081094544C71240020 @default.
- W3081094544 hasConceptScore W3081094544C8010536 @default.
- W3081094544 hasLocation W30810945441 @default.
- W3081094544 hasOpenAccess W3081094544 @default.
- W3081094544 hasPrimaryLocation W30810945441 @default.
- W3081094544 hasRelatedWork W2012128185 @default.
- W3081094544 hasRelatedWork W2013119692 @default.
- W3081094544 hasRelatedWork W2030760235 @default.
- W3081094544 hasRelatedWork W2036885403 @default.