FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3081272657> ?p ?o ?g. }

• W3081272657 endingPage "111429" @default.
• W3081272657 startingPage "111429" @default.
• W3081272657 abstract "Poly(glycerol sebacate) (PGS) is a versatile biodegradable biomaterial on account of its adjustable mechanical properties as an elastomeric polyester. Nevertheless, it has shown dissimilar results when synthesised by different research groups under equivalent synthesis conditions. This lack of reproducibility proves how crucial it is to understand the effect of the parameters involved on its manufacturing and characterize the polymer networks obtained. Several studies have been conducted in recent years to understand the role of temperature, time, and the molar ratio of its monomers, while the influence of the atmosphere applied during its pre-polymerisation remained unknown. The results obtained here allow for a better understanding about the effect of inert (Ar and N2) and oxidative (oxygen, dry air, and humid air) atmospheres on the extent of the reaction. The molecular pattern of intermediate pre-polymers and the gelation time and morphology of their corresponding cured PGS networks were studied as well. Overall, inert atmospheres promote a rather linear growth of macromers, with scarce branches, resulting in loose elastomers with long chains mainly crosslinked. Conversely, oxygen in the latter atmospheres promotes branching through secondary hydroxyl groups, leading to less-crosslinked ‘defective’ networks. In this way, the pre-polymerisation atmosphere could be used advantageously to adjust the reactivity of secondary hydroxyls, in order to modulate branching in the elastomeric PGS networks obtained to suit the properties required in a particular application." @default.
• W3081272657 created "2020-09-01" @default.
• W3081272657 creator A5000966223 @default.
• W3081272657 creator A5007663236 @default.
• W3081272657 creator A5044488708 @default.
• W3081272657 date "2021-02-01" @default.
• W3081272657 modified "2023-09-25" @default.
• W3081272657 title "Influence of pre-polymerisation atmosphere on the properties of pre- and poly(glycerol sebacate)" @default.
• W3081272657 cites W1847633073 @default.
• W3081272657 cites W1966735287 @default.
• W3081272657 cites W1968767333 @default.
• W3081272657 cites W1974469532 @default.
• W3081272657 cites W1980328470 @default.
• W3081272657 cites W1981833215 @default.
• W3081272657 cites W1989652540 @default.
• W3081272657 cites W1992112195 @default.
• W3081272657 cites W1994054444 @default.
• W3081272657 cites W1998732209 @default.
• W3081272657 cites W2000537455 @default.
• W3081272657 cites W2002783172 @default.
• W3081272657 cites W2011773003 @default.
• W3081272657 cites W201298804 @default.
• W3081272657 cites W2028803645 @default.
• W3081272657 cites W2076820713 @default.
• W3081272657 cites W2080178959 @default.
• W3081272657 cites W2087515198 @default.
• W3081272657 cites W2091172685 @default.
• W3081272657 cites W2096538172 @default.
• W3081272657 cites W2098504026 @default.
• W3081272657 cites W2098904414 @default.
• W3081272657 cites W2163545688 @default.
• W3081272657 cites W2170159489 @default.
• W3081272657 cites W2170459793 @default.
• W3081272657 cites W2301563261 @default.
• W3081272657 cites W2333953251 @default.
• W3081272657 cites W2468210577 @default.
• W3081272657 cites W2531989901 @default.
• W3081272657 cites W2557111495 @default.
• W3081272657 cites W2568533099 @default.
• W3081272657 cites W2599065484 @default.
• W3081272657 cites W2608302194 @default.
• W3081272657 cites W2616265200 @default.
• W3081272657 cites W2625009403 @default.
• W3081272657 cites W2748750969 @default.
• W3081272657 cites W2790968646 @default.
• W3081272657 cites W2911455807 @default.
• W3081272657 cites W2979733023 @default.
• W3081272657 doi "https://doi.org/10.1016/j.msec.2020.111429" @default.
• W3081272657 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33321580" @default.
• W3081272657 hasPublicationYear "2021" @default.
• W3081272657 type Work @default.
• W3081272657 sameAs 3081272657 @default.
• W3081272657 citedByCount "8" @default.
• W3081272657 countsByYear W30812726572021 @default.
• W3081272657 countsByYear W30812726572022 @default.
• W3081272657 countsByYear W30812726572023 @default.
• W3081272657 crossrefType "journal-article" @default.
• W3081272657 hasAuthorship W3081272657A5000966223 @default.
• W3081272657 hasAuthorship W3081272657A5007663236 @default.
• W3081272657 hasAuthorship W3081272657A5044488708 @default.
• W3081272657 hasBestOaLocation W30812726572 @default.
• W3081272657 hasConcept C119394753 @default.
• W3081272657 hasConcept C121332964 @default.
• W3081272657 hasConcept C127413603 @default.
• W3081272657 hasConcept C154256306 @default.
• W3081272657 hasConcept C159985019 @default.
• W3081272657 hasConcept C161790260 @default.
• W3081272657 hasConcept C166940927 @default.
• W3081272657 hasConcept C178790620 @default.
• W3081272657 hasConcept C185592680 @default.
• W3081272657 hasConcept C188027245 @default.
• W3081272657 hasConcept C192562407 @default.
• W3081272657 hasConcept C206175624 @default.
• W3081272657 hasConcept C2780881558 @default.
• W3081272657 hasConcept C2994067411 @default.
• W3081272657 hasConcept C38052585 @default.
• W3081272657 hasConcept C42360764 @default.
• W3081272657 hasConcept C44228677 @default.
• W3081272657 hasConcept C521977710 @default.
• W3081272657 hasConcept C540031477 @default.
• W3081272657 hasConcept C55766333 @default.
• W3081272657 hasConcept C65440619 @default.
• W3081272657 hasConcept C97355855 @default.
• W3081272657 hasConceptScore W3081272657C119394753 @default.
• W3081272657 hasConceptScore W3081272657C121332964 @default.
• W3081272657 hasConceptScore W3081272657C127413603 @default.
• W3081272657 hasConceptScore W3081272657C154256306 @default.
• W3081272657 hasConceptScore W3081272657C159985019 @default.
• W3081272657 hasConceptScore W3081272657C161790260 @default.
• W3081272657 hasConceptScore W3081272657C166940927 @default.
• W3081272657 hasConceptScore W3081272657C178790620 @default.
• W3081272657 hasConceptScore W3081272657C185592680 @default.
• W3081272657 hasConceptScore W3081272657C188027245 @default.
• W3081272657 hasConceptScore W3081272657C192562407 @default.
• W3081272657 hasConceptScore W3081272657C206175624 @default.
• W3081272657 hasConceptScore W3081272657C2780881558 @default.
• W3081272657 hasConceptScore W3081272657C2994067411 @default.
• W3081272657 hasConceptScore W3081272657C38052585 @default.

• next