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- W3081343485 abstract "Abstract Fluorinated organophosphorus(V) compounds are a very versatile class of compounds, but the synthetic methods available to make them bear the disadvantages of 1) occasional handling of toxic or pyrophoric P III starting materials and 2) a dependence on hazardous fluorinating reagents such as XeF 2 . Herein, we present a simple solution and introduce a deoxygenative fluorination (DOF) approach that utilizes easy‐to‐handle phosphine oxides as starting materials and effectively replaces harsh fluorinating reagents by a combination of oxalyl chloride and potassium fluoride. The reaction has proven to be general, as R 3 PF 2 , R 2 PF 3 , and RPF 4 compounds (as well as various cations and anions derived from these) are accessible in good yields and on up to a multi‐gram scale. DFT calculations were used to bolster our observations. Notably, the discovery of this new method led to a convenient synthesis of 1) new difluorophosphonium ions, 2) hexafluorophosphate salts, and 3) fluorinated antimony‐ and arsenic‐ compounds." @default.
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- W3081343485 date "2020-10-02" @default.
- W3081343485 modified "2023-10-07" @default.
- W3081343485 title "Deoxygenative Fluorination of Phosphine Oxides: A General Route to Fluorinated Organophosphorus(V) Compounds and Beyond" @default.
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- W3081343485 doi "https://doi.org/10.1002/anie.202010943" @default.
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