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• W3081522006 startingPage "8587" @default.
• W3081522006 abstract "The host structure of the new phosphor Sr6(BO3)3BN2:Eu2+ crystallizes tetragonally (Sr6(BO3)3BN2, P42/mbc, Z = 8, a = 12.8173(3) Å, b = 14.0740(5) Å, Rint = 0.037, R1 = 0.052, and wR2 = 0.121) and features the two borate anions BN23– localized within a channel formed by Sr2+ and BO33– in the same material. Furthermore, spectroscopic data (infrared, Raman, and UV–vis) are discussed, and the first results on the luminescence properties of Sr6(BO3)3BN2:Eu2+ with an emission–emission peaking at 618 nm upon excitation peaking at 465 nm are presented. Electronic structure calculations yield a band gap of 3.91 eV—with the nitrogen atoms being responsible for the smaller band gap than oxoborates—and confirm the disorder of the BN23– ions." @default.
• W3081522006 created "2020-09-08" @default.
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• W3081522006 date "2020-09-01" @default.
• W3081522006 modified "2023-09-26" @default.
• W3081522006 title "Sr₆(BO₃)₃BN₂: An Oxido–Nitrido–Borate Phosphor Featuring BN₂ Dumbbells" @default.
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• W3081522006 doi "https://doi.org/10.1021/acs.chemmater.0c02925" @default.
• W3081522006 hasPublicationYear "2020" @default.
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