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• W3081647801 abstract "Abstract The synthesis and characterization of five new chiral dialkyltin complexes of N -salicylidene- L -valine, [2-O-3-R-5-R'C 6 H 2 C(H)=NCH(CH(CH 3 ) 2 )C(O)O]SnR'' 2 (R, R', R'' = H, H, Me ( 1 ); H, Br, Me ( 2 ); OMe, H, Et ( 3 ); Br, Br, n -Bu ( 4 ); CH(OMe) 2 , Me, n -Bu ( 5 )), have been reported. Compounds 1-5 are all ( S )-enantiomers, and their crystal structures have been studied. Compound 1 displays a trimeric macrocyclic structure in which the coordination environment of each tin atom is a distorted [SnC 2 NO 3 ] octahedron. In complexes 2-5 , the tin atom has an intermediate geometry between trigonal bipyramidal and square pyramidal, and 3 is closer to a square pyramid. In crystals, a zigzag supramolecular chain is formed by the intermolecular C-H…O, O-H…O or Sn…O interactions." @default.
• W3081647801 created "2020-09-08" @default.
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• W3081647801 date "2020-01-01" @default.
• W3081647801 modified "2023-10-16" @default.
• W3081647801 title "Synthesis and structural characterization of dialkyltin complexes of <i>N</i>-salicylidene-<i>L</i>-valine" @default.
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• W3081647801 doi "https://doi.org/10.1515/mgmc-2020-0017" @default.
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