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- W3081718753 endingPage "22522" @default.
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- W3081718753 abstract "Bioconjugation methods using visible-light photocatalysis have emerged as powerful synthetic tools for the selective modification of biomolecules under mild reaction conditions. However, the number of photochemical transformations that allow successful protein bioconjugation is still limited because of the need for stringent reaction conditions. Herein, we report that a newly developed water-compatible fluorescent photosensitizer QPEG can be used for visible-light-induced cysteine-specific bioconjugation for the installation of QPEG by exploiting its intrinsic photosensitizing ability to activate the S-H bond of cysteine. The slightly modified QCAT enables the effective photocatalytic cysteine-specific conjugation of biologically relevant groups. The superior reactivity and cysteine selectivity of this methodology was further corroborated by traceless bioconjugation with a series of complex peptides and proteins under biocompatible conditions." @default.
- W3081718753 created "2020-09-08" @default.
- W3081718753 creator A5034349813 @default.
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- W3081718753 creator A5048760496 @default.
- W3081718753 creator A5062553900 @default.
- W3081718753 date "2020-10-08" @default.
- W3081718753 modified "2023-09-29" @default.
- W3081718753 title "Visible‐Light‐Induced Cysteine‐Specific Bioconjugation: Biocompatible Thiol–Ene Click Chemistry" @default.
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- W3081718753 doi "https://doi.org/10.1002/anie.202010217" @default.
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