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• W3081828618 endingPage "1971" @default.
• W3081828618 startingPage "1971" @default.
• W3081828618 abstract "Green nanocomposites from rosin-limonene (Ros-Lim) copolymers based on Algerian organophilic-clay named Maghnite-CTA+ (Mag-CTA+) were prepared by in-situ polymerization using different amounts (1, 5 and 10% by weight) of Mag-CTA+ and azobisisobutyronitrile as a catalyst. The Mag-CTA+ is an organophilic montmorillonite silicate clay prepared through a direct exchange process; the clay was modified by ultrasonic-assisted method using cetyltrimethylammonuim bromide in which it used as green nano-filler.The preparation method of nanocomposites was studied in order to determine and improve structural, morphological, mechanical and thermal properties ofsin.The structure and morphology of the obtained nanocomposites(Ros-Lim/Mag-CTA+) were determined using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electronic microscopy and transmission electronic microscopy. The analyses confirmed the chemical modification of clay layers and the intercalation of rosin-limonene copolymer within the organophilic-clay sheets. An exfoliated structure was obtained for the lower amount of clay (1% wt of Mag-CTA+), while intercalated structures were detected for high amounts of clay (5 and 10% wt of Mag-CTA+). The thermal properties of the nanocomposites were studied by thermogravimetric analysis (TGA) and show a significant improvement inthe thermal stability of the obtained nanocomposites compared to the purerosin-limonene copolymer (a degradation temperature up to 280 °C)." @default.
• W3081828618 created "2020-09-08" @default.
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• W3081828618 date "2020-08-30" @default.
• W3081828618 modified "2023-10-18" @default.
• W3081828618 title "Green Nanocomposites from Rosin-Limonene Copolymer and Algerian Clay" @default.
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• W3081828618 doi "https://doi.org/10.3390/polym12091971" @default.
• W3081828618 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7565992" @default.
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• W3081828618 hasPublicationYear "2020" @default.
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