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- W3082024798 abstract "A novel amorphous iron metal-organic framework (NEU-2 = Fe(BPDI)(Py) 2 , BPDI = N,N'bis(glycinyl)pyromellitic diimide; Py = pyridine) with multichannel pore systems is synthesized, and subsequently tested as class 1 sorbent by evaluating its CO 2 capture capacity. Whereas the meso- and macro-pores present in NEU-2 are loaded with polietilenimina (PEI), micropores are maintained accessible for CO 2 diffusion. Tests at different temperatures and cyclic adsorption-desorption experiments are performed to examine CO 2 uptake and amine efficiency evolution. Moreover, the diffusion resistance present within the pores of the material is measured by comparing the fast uptake at the beginning of the capture (pseudo-kinetic regime) to the slow uptake at the end of capture towards equilibrium (pseudo-diffusive regime). It is also reported a comparative study of the CO 2 capture capacity of amorphous NEU-2 and crystalline NEU-1c. This research demonstrates that the ordered crystalline state of MOFs is not a requirement for gas uptake, establishing novel amorphous MOFs with hierarchical porosity as promising materials for CO 2 ‐capture applications. It is evidenced that amorphous MOFs may facilitate a variety of chemical separations due to its framework flexibility and, ultimately, its guest-responsive capability. • Design, synthesis and structure elucidation of an amorphous iron MOF (NEU-2). • NEU-2 shows a hierarchical pore distribution. • Amorphous MOFs as efficient designs for gas uptake. • NEU-2 addresses the trade-off between amine loading and low access to amine sites." @default.
- W3082024798 created "2020-09-08" @default.
- W3082024798 creator A5033837289 @default.
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- W3082024798 date "2021-01-01" @default.
- W3082024798 modified "2023-09-29" @default.
- W3082024798 title "Synthesis of a novel amorphous metal organic framework with hierarchical porosity for adsorptive gas separation" @default.
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- W3082024798 cites W1969180055 @default.
- W3082024798 cites W1973699051 @default.
- W3082024798 cites W1976051397 @default.
- W3082024798 cites W1984939881 @default.
- W3082024798 cites W1989439140 @default.
- W3082024798 cites W1991999330 @default.
- W3082024798 cites W1998523963 @default.
- W3082024798 cites W2004131161 @default.
- W3082024798 cites W2017012055 @default.
- W3082024798 cites W2021869469 @default.
- W3082024798 cites W2024831874 @default.
- W3082024798 cites W2037056665 @default.
- W3082024798 cites W2046029447 @default.
- W3082024798 cites W2055230539 @default.
- W3082024798 cites W2069662853 @default.
- W3082024798 cites W2070227796 @default.
- W3082024798 cites W2073178380 @default.
- W3082024798 cites W2076949647 @default.
- W3082024798 cites W2080217338 @default.
- W3082024798 cites W2080615720 @default.
- W3082024798 cites W2081646891 @default.
- W3082024798 cites W2110848427 @default.
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- W3082024798 cites W2148931401 @default.
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- W3082024798 cites W2156142084 @default.
- W3082024798 cites W2162170130 @default.
- W3082024798 cites W2163242195 @default.
- W3082024798 cites W2276923202 @default.
- W3082024798 cites W2310642646 @default.
- W3082024798 cites W2314230014 @default.
- W3082024798 cites W2318352588 @default.
- W3082024798 cites W2329977751 @default.
- W3082024798 cites W2330340940 @default.
- W3082024798 cites W2332393429 @default.
- W3082024798 cites W2332801228 @default.
- W3082024798 cites W2333263273 @default.
- W3082024798 cites W2334085604 @default.
- W3082024798 cites W2520516259 @default.
- W3082024798 cites W2581877533 @default.
- W3082024798 cites W2583444253 @default.
- W3082024798 cites W2609016386 @default.
- W3082024798 cites W2623366189 @default.
- W3082024798 cites W2737631159 @default.
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- W3082024798 cites W2781593349 @default.
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- W3082024798 cites W2908141075 @default.
- W3082024798 cites W2912041441 @default.
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- W3082024798 cites W2935928978 @default.
- W3082024798 cites W2939907653 @default.
- W3082024798 cites W2939974222 @default.
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- W3082024798 doi "https://doi.org/10.1016/j.micromeso.2020.110600" @default.
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