FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3082140242> ?p ?o ?g. }

• W3082140242 endingPage "1347" @default.
• W3082140242 startingPage "1333" @default.
• W3082140242 abstract "Through the use of N-[2′-ferrocenylformamido-ethyl]-cis-5-norbornene-exo-2,3-dicarboximide (NFc) and N-[2′-adamantylformamido-ethyl]-cis-5-norbornene-exo-2,3-dicarboximide (NAd), we report the fabrication of two novel supramolecular norbornene monomers, NFc@β-CD and NAd@β-CD, through β-cyclodextrin (β-CD)/ferrrocene(Fc)- and β-CD/adamantane (Ad)-based host–guest complexation. The formation and structure of the two monomers were verified by various techniques, such as 1H and 13C NMR, 2D NOESY, IR and UV–vis spectroscopic methods. The ROMP (ring-opening metathesis polymerization) feasibility of the two supramolecular monomers was further confirmed by the successful preparation of two homopolymers (P(NFc@β-CD) and P(NAd@β-CD)) and two diblock copolymers (PNFc-b-P(NAd@β-CD) and P(NFc@β-CD)-b-P(NAd@β-CD)). The prepared polymers were adequately analyzed using 1H and 13C NMR, IR, UV–vis, end-group analysis and GPC methods. Based on the obtained results, we believe that (1) both supramolecular monomers exhibited “living” and “controlled” ROMP reactions; (2) the β-CD/Fc and β-CD/Ad inclusion complexes were not disassembled during the ROMP reactions of the two supramolecular monomers; and (3) the functional groups of β-CD had a negligible effect on the catalytic activity of the third-generation Grubbs’ catalyst. In short, this work indicated that the direct ROMP of β-CD-containing supramolecular monomers was a feasible route for preparing supramolecular polynorbornene-based homopolymers and copolymers, and this route is expected to have great potential for the preparation of various supramolecular polynorbornenes and functional materials. Two novel supramolecular norbornene monomers were prepared according to β-cyclodextrin–ferrocene (/adamantane) host–guest interactions and exhibited both the “living” and “controlled” ROMP characteristics with the aid of the third-generation Grubbs’ catalyst for the construction of corresponding supramolecular homopolymers and diblock copolymers." @default.
• W3082140242 created "2020-09-08" @default.
• W3082140242 creator A5011221080 @default.
• W3082140242 creator A5024130438 @default.
• W3082140242 creator A5046781760 @default.
• W3082140242 creator A5052386161 @default.
• W3082140242 creator A5061264097 @default.
• W3082140242 creator A5066716873 @default.
• W3082140242 date "2020-09-01" @default.
• W3082140242 modified "2023-09-27" @default.
• W3082140242 title "ROMP of supramolecular norbornene monomers containing β-cyclodextrin–ferrocene (/adamantane) inclusion complexes" @default.
• W3082140242 cites W2005546983 @default.
• W3082140242 cites W2007252698 @default.
• W3082140242 cites W2019033473 @default.
• W3082140242 cites W2030397121 @default.
• W3082140242 cites W2059421348 @default.
• W3082140242 cites W2059968498 @default.
• W3082140242 cites W2071756380 @default.
• W3082140242 cites W2079934765 @default.
• W3082140242 cites W2082264985 @default.
• W3082140242 cites W2088780699 @default.
• W3082140242 cites W2106574596 @default.
• W3082140242 cites W2143815275 @default.
• W3082140242 cites W2266726802 @default.
• W3082140242 cites W2296355803 @default.
• W3082140242 cites W2314961732 @default.
• W3082140242 cites W2596868639 @default.
• W3082140242 cites W2610816916 @default.
• W3082140242 cites W2746274537 @default.
• W3082140242 cites W2766380923 @default.
• W3082140242 cites W2783194534 @default.
• W3082140242 cites W2801617286 @default.
• W3082140242 cites W2890039659 @default.
• W3082140242 cites W2896082021 @default.
• W3082140242 cites W2897774729 @default.
• W3082140242 cites W2905329608 @default.
• W3082140242 cites W2909311827 @default.
• W3082140242 cites W2909517634 @default.
• W3082140242 cites W2915241774 @default.
• W3082140242 cites W2937039196 @default.
• W3082140242 cites W2937680163 @default.
• W3082140242 cites W2939447504 @default.
• W3082140242 cites W2949308244 @default.
• W3082140242 cites W2956953798 @default.
• W3082140242 cites W2981476520 @default.
• W3082140242 cites W2988090151 @default.
• W3082140242 cites W3006471871 @default.
• W3082140242 doi "https://doi.org/10.1038/s41428-020-00398-3" @default.
• W3082140242 hasPublicationYear "2020" @default.
• W3082140242 type Work @default.
• W3082140242 sameAs 3082140242 @default.
• W3082140242 citedByCount "2" @default.
• W3082140242 countsByYear W30821402422022 @default.
• W3082140242 countsByYear W30821402422023 @default.
• W3082140242 crossrefType "journal-article" @default.
• W3082140242 hasAuthorship W3082140242A5011221080 @default.
• W3082140242 hasAuthorship W3082140242A5024130438 @default.
• W3082140242 hasAuthorship W3082140242A5046781760 @default.
• W3082140242 hasAuthorship W3082140242A5052386161 @default.
• W3082140242 hasAuthorship W3082140242A5061264097 @default.
• W3082140242 hasAuthorship W3082140242A5066716873 @default.
• W3082140242 hasBestOaLocation W30821402421 @default.
• W3082140242 hasConcept C130929614 @default.
• W3082140242 hasConcept C153914509 @default.
• W3082140242 hasConcept C15920480 @default.
• W3082140242 hasConcept C166940927 @default.
• W3082140242 hasConcept C178790620 @default.
• W3082140242 hasConcept C185592680 @default.
• W3082140242 hasConcept C188027245 @default.
• W3082140242 hasConcept C2779433975 @default.
• W3082140242 hasConcept C2779556047 @default.
• W3082140242 hasConcept C2780227895 @default.
• W3082140242 hasConcept C2780547246 @default.
• W3082140242 hasConcept C32909587 @default.
• W3082140242 hasConcept C44228677 @default.
• W3082140242 hasConcept C521977710 @default.
• W3082140242 hasConcept C93275456 @default.
• W3082140242 hasConceptScore W3082140242C130929614 @default.
• W3082140242 hasConceptScore W3082140242C153914509 @default.
• W3082140242 hasConceptScore W3082140242C15920480 @default.
• W3082140242 hasConceptScore W3082140242C166940927 @default.
• W3082140242 hasConceptScore W3082140242C178790620 @default.
• W3082140242 hasConceptScore W3082140242C185592680 @default.
• W3082140242 hasConceptScore W3082140242C188027245 @default.
• W3082140242 hasConceptScore W3082140242C2779433975 @default.
• W3082140242 hasConceptScore W3082140242C2779556047 @default.
• W3082140242 hasConceptScore W3082140242C2780227895 @default.
• W3082140242 hasConceptScore W3082140242C2780547246 @default.
• W3082140242 hasConceptScore W3082140242C32909587 @default.
• W3082140242 hasConceptScore W3082140242C44228677 @default.
• W3082140242 hasConceptScore W3082140242C521977710 @default.
• W3082140242 hasConceptScore W3082140242C93275456 @default.
• W3082140242 hasIssue "12" @default.
• W3082140242 hasLocation W30821402421 @default.
• W3082140242 hasOpenAccess W3082140242 @default.
• W3082140242 hasPrimaryLocation W30821402421 @default.
• W3082140242 hasRelatedWork W1554479084 @default.
• W3082140242 hasRelatedWork W2019180281 @default.

• next