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- W3082227751 endingPage "22583" @default.
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- W3082227751 abstract "Hierarchical carbohydrate architectures serve multiple roles in nature. Hardly any correlations between the carbohydrate chemical structures and the material properties are available due to the lack of standards and suitable analytic techniques. Therefore, designer carbohydrate materials remain highly unexplored, as compared to peptides and nucleic acids. A synthetic D-glucose disaccharide, DD, was chosen as a model to explore carbohydrate materials. Microcrystal electron diffraction (MicroED), optimized for oligosaccharides, revealed that DD assembled into highly crystalline left-handed helical fibers. The supramolecular architecture was correlated to the local crystal organization, allowing for the design of the enantiomeric right-handed fibers, based on the L-glucose disaccharide, LL, or flat lamellae, based on the racemic mixture. Tunable morphologies and mechanical properties suggest the potential of carbohydrate materials for nanotechnology applications." @default.
- W3082227751 created "2020-09-08" @default.
- W3082227751 creator A5008512379 @default.
- W3082227751 creator A5024187155 @default.
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- W3082227751 creator A5040694983 @default.
- W3082227751 creator A5046655944 @default.
- W3082227751 creator A5062856177 @default.
- W3082227751 date "2020-10-07" @default.
- W3082227751 modified "2023-10-04" @default.
- W3082227751 title "Supramolecular Assembly and Chirality of Synthetic Carbohydrate Materials" @default.
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- W3082227751 doi "https://doi.org/10.1002/anie.202008153" @default.
- W3082227751 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7756587" @default.
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- W3082227751 hasPublicationYear "2020" @default.
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