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- W3082453313 abstract "The applications of mixed ionic-electronic conductors are limited due to phase instability under a high direct current and large temperature difference. Here, it is shown that Cu2 Se is stabilized through regulating the behaviors of Cu+ ions and electrons in a Schottky heterojunction between the Cu2 Se host matrix and in-situ-formed BiCuSeO nanoparticles. The accumulation of Cu+ ions via an ionic capacitive effect at the Schottky junction under the direct current modifies the space-charge distribution in the electric double layer, which blocks the long-range migration of Cu+ and produces a drastic reduction of Cu+ ion migration by nearly two orders of magnitude. Moreover, this heterojunction impedes electrons transferring from BiCuSeO to Cu2 Se, obstructing the reduction reaction of Cu+ into Cu metal at the interface and hence stabilizes the β-Cu2 Se phase. Furthermore, incorporation of BiCuSeO in Cu2 Se optimizes the carrier concentration and intensifies phonon scattering, contributing to the peak figure of merit ZT value of ≈2.7 at 973 K and high average ZT value of ≈1.5 between 400 and 973 K for the Cu2 Se/BiCuSeO composites. This discovery provides a new avenue for stabilizing mixed ionic-electronic conduction thermoelectrics, and gives fresh insights into controlling ion migration in these ionic-transport-dominated materials." @default.
- W3082453313 created "2020-09-08" @default.
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- W3082453313 date "2020-09-02" @default.
- W3082453313 modified "2023-10-15" @default.
- W3082453313 title "Blocking Ion Migration Stabilizes the High Thermoelectric Performance in Cu <sub>2</sub> Se Composites" @default.
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- W3082453313 doi "https://doi.org/10.1002/adma.202003730" @default.
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