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- W3082775991 endingPage "13571" @default.
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- W3082775991 abstract "Sterically demanding secondary potassium phosphides (4) were synthesized and investigated. Reaction with halophosphanes (5) yields diphosphanes (6), whereas reaction with CS2 yields phosphanyl dithioformates (10). These can be further converted to the corresponding phosphanyl esters of dithioformic acid R2P–C(S)S–PR2 (8). One of these thioesters (8) was found to undergo a migration reaction, resulting in the formation of a phosphanylthioketone with an additional phosphanylthiolate group (9), which was used as a chiral ligand in gold coordination chemistry. The phosphanyl migration reaction was investigated by spectroscopic and theoretical methods, revealing a first-order reaction via a cyclic transition state. All species mentioned were fully characterized." @default.
- W3082775991 created "2020-09-08" @default.
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- W3082775991 date "2020-09-01" @default.
- W3082775991 modified "2023-09-25" @default.
- W3082775991 title "Synthesis of Sterically Demanding Secondary Phosphides and Diphosphanes and Their Utilization in Small-Molecule Activation" @default.
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- W3082775991 doi "https://doi.org/10.1021/acs.inorgchem.0c01934" @default.
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