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- W3082932016 abstract "In this study, we report that selective aerobic oxidation of allyl phenyl ethers is attained by a Pd catalyst/polyoxometalate hybrid system to yield corresponding methyl ketones in water-enriched acetonitrile. The Pd(OAc)2/H5PV2Mo10O40 system exhibits higher conversions and yields of corresponding methyl ketone by Wacker-type oxidation of allyl phenyl ether as compared with the conventional PdCl2/CuCl2 system. The higher yields are attributed to the efficient re-oxidation of Pd0 to Pd2+ by H5PV2Mo10O40 using O2 as an oxidant as evidenced by electrochemical measurements. A reduced species of H5PV2Mo10O40 by Pd0 during the catalytic oxidation is revealed by UV–vis spectral measurements. The use of PdCl2 in place of Pd(OAc)2 in combination with [PV2Mo10O40]5− bearing tetraalkylammonium counter cations has also exhibited comparable conversions and product yields in the Wacker-type oxidation of allyl phenyl ethers. Para-substituted allyl phenyl ether derivatives are successfully oxidized in the Pd catalyst/polyoxometalate system to yield corresponding methyl ketones. The initial rate of products of para-substituted methyl ketones depended on the electronic effect of the substituents in which allyl phenyl ethers with electron-donating groups have accelerated the initial rate in the Pd catalyst/polyoxometalate system." @default.
- W3082932016 created "2020-09-08" @default.
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- W3082932016 date "2020-11-01" @default.
- W3082932016 modified "2023-09-23" @default.
- W3082932016 title "Selective aerobic oxidation of allyl phenyl ether to methyl ketone by palladium–polyoxometalate hybrid catalysts" @default.
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- W3082932016 doi "https://doi.org/10.1016/j.mcat.2020.111178" @default.
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