Matches in SemOpenAlex for { <https://semopenalex.org/work/W3083009747> ?p ?o ?g. }
- W3083009747 endingPage "793" @default.
- W3083009747 startingPage "793" @default.
- W3083009747 abstract "A series of three different solvatomorphs of a new iron(II) complex with N,N′-disubstituted 2,6-bis(pyrazol-3-yl)pyridine, including those with the same lattice solvent, has been identified by X-ray diffraction under the same crystallization conditions with the metal ion trapped in the different spin states. A thermally induced switching between them, however, occurs in a solution, as unambiguously confirmed by the Evans technique and an analysis of paramagnetic chemical shifts, both based on variable-temperature NMR spectroscopy. The observed stabilization of the high-spin state by an electron-donating substituent contributes to the controversial results for the iron(II) complexes of 2,6-bis(pyrazol-3-yl)pyridines, preventing ‘molecular’ design of their spin-crossover activity; the synthesized complex being only the fourth of the spin-crossover (SCO)-active kind with an N,N′-disubstituted ligand." @default.
- W3083009747 created "2020-09-11" @default.
- W3083009747 creator A5013201211 @default.
- W3083009747 creator A5020874089 @default.
- W3083009747 creator A5029487963 @default.
- W3083009747 creator A5061567341 @default.
- W3083009747 creator A5069450250 @default.
- W3083009747 date "2020-09-08" @default.
- W3083009747 modified "2023-09-24" @default.
- W3083009747 title "Spin State Behavior of A Spin-Crossover Iron(II) Complex with N,N′-Disubstituted 2,6-bis(pyrazol-3-yl)pyridine: A Combined Study by X-ray Diffraction and NMR Spectroscopy" @default.
- W3083009747 cites W1905183855 @default.
- W3083009747 cites W1946726626 @default.
- W3083009747 cites W1966555688 @default.
- W3083009747 cites W1968352183 @default.
- W3083009747 cites W1969360633 @default.
- W3083009747 cites W1977633617 @default.
- W3083009747 cites W1983783138 @default.
- W3083009747 cites W1986591357 @default.
- W3083009747 cites W1988091937 @default.
- W3083009747 cites W1989895072 @default.
- W3083009747 cites W1995824506 @default.
- W3083009747 cites W1996410305 @default.
- W3083009747 cites W1997884116 @default.
- W3083009747 cites W2009785271 @default.
- W3083009747 cites W2012488984 @default.
- W3083009747 cites W2014555163 @default.
- W3083009747 cites W2016150274 @default.
- W3083009747 cites W2017282658 @default.
- W3083009747 cites W2028556966 @default.
- W3083009747 cites W2030524493 @default.
- W3083009747 cites W2032719166 @default.
- W3083009747 cites W2033171898 @default.
- W3083009747 cites W2034641813 @default.
- W3083009747 cites W2037349442 @default.
- W3083009747 cites W2045894490 @default.
- W3083009747 cites W2047826240 @default.
- W3083009747 cites W2054250629 @default.
- W3083009747 cites W2054971145 @default.
- W3083009747 cites W2059205366 @default.
- W3083009747 cites W2064311755 @default.
- W3083009747 cites W2064676853 @default.
- W3083009747 cites W2067718414 @default.
- W3083009747 cites W2077858819 @default.
- W3083009747 cites W2078644155 @default.
- W3083009747 cites W2079935930 @default.
- W3083009747 cites W2080447728 @default.
- W3083009747 cites W2092831810 @default.
- W3083009747 cites W2099037802 @default.
- W3083009747 cites W2115315764 @default.
- W3083009747 cites W2117520491 @default.
- W3083009747 cites W2119060556 @default.
- W3083009747 cites W2119547517 @default.
- W3083009747 cites W2122329909 @default.
- W3083009747 cites W2127602011 @default.
- W3083009747 cites W2132454074 @default.
- W3083009747 cites W2145408306 @default.
- W3083009747 cites W2160790360 @default.
- W3083009747 cites W2162277367 @default.
- W3083009747 cites W2252562185 @default.
- W3083009747 cites W2265525426 @default.
- W3083009747 cites W2289931318 @default.
- W3083009747 cites W2300135740 @default.
- W3083009747 cites W2330291315 @default.
- W3083009747 cites W2337217952 @default.
- W3083009747 cites W2340715265 @default.
- W3083009747 cites W2342997537 @default.
- W3083009747 cites W2402454737 @default.
- W3083009747 cites W2482948743 @default.
- W3083009747 cites W2503806286 @default.
- W3083009747 cites W2557407764 @default.
- W3083009747 cites W2569756618 @default.
- W3083009747 cites W2592152709 @default.
- W3083009747 cites W2603360340 @default.
- W3083009747 cites W2603702524 @default.
- W3083009747 cites W2605429899 @default.
- W3083009747 cites W2606898172 @default.
- W3083009747 cites W2618436321 @default.
- W3083009747 cites W2725423922 @default.
- W3083009747 cites W2739439285 @default.
- W3083009747 cites W2767530734 @default.
- W3083009747 cites W2770345794 @default.
- W3083009747 cites W2770672409 @default.
- W3083009747 cites W2774354754 @default.
- W3083009747 cites W2775540929 @default.
- W3083009747 cites W2799923297 @default.
- W3083009747 cites W2809094472 @default.
- W3083009747 cites W2889106116 @default.
- W3083009747 cites W2889855435 @default.
- W3083009747 cites W2897166535 @default.
- W3083009747 cites W2897680618 @default.
- W3083009747 cites W2898657291 @default.
- W3083009747 cites W2899956317 @default.
- W3083009747 cites W2900776336 @default.
- W3083009747 cites W2930600440 @default.
- W3083009747 cites W2943923497 @default.
- W3083009747 cites W2951254503 @default.
- W3083009747 cites W2955756760 @default.
- W3083009747 cites W2964302883 @default.