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• W3083263983 startingPage "23174" @default.
• W3083263983 abstract "Abstract The fluoronitrenoid metal complexes FNCoF 2 and FNRhF 2 as well as the first ternary Rh VI and Ir VI complexes NIrF 3 and NRhF 3 are described. They were obtained by the reaction of excited Group‐9 metal atoms with NF 3 and their IR spectra, isolated in solid rare gases (neon and argon), were recorded. Aided by the observed 14/15 N isotope shifts and quantum‐chemical predictions, all four stretching fundamentals of the novel complexes were safely assigned. The F−N stretching frequencies of the fluoronitrenoid complexes FNCoF 2 (1056.8 cm −1 ) and FNRhF 2 (872.6 cm −1 ) are very different and their N−M bonds vary greatly. In FNCoF 2 , the FN ligand is singly bonded to Co and bears considerable iminyl/nitrene radical character, while the N−Rh bond in FNRhF 2 is a strong double bond with comparatively strong σ‐ and π‐bonds. The anticipated rearrangement of FNCoF 2 to the nitrido Co VI complex is predicted to be endothermic and was not observed." @default.
• W3083263983 created "2020-09-11" @default.
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• W3083263983 date "2020-10-15" @default.
• W3083263983 modified "2023-10-18" @default.
• W3083263983 title "Fluoro Nitrenoid Complexes FN=MF ₂ (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF ₃" @default.
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• W3083263983 doi "https://doi.org/10.1002/anie.202010950" @default.
• W3083263983 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7756499" @default.
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