Matches in SemOpenAlex for { <https://semopenalex.org/work/W3083323213> ?p ?o ?g. }
- W3083323213 endingPage "8201" @default.
- W3083323213 startingPage "8195" @default.
- W3083323213 abstract "Photoelectron imaging of the isolated adenosine-5′-triphosphate dianion excited to the 1ππ* states reveals that electron emission is predominantly parallel to the polarization axis of the light and arises from subpicosecond electron tunneling through the repulsive Coulomb barrier (RCB). The computed RCB shows that the most probable electron emission site is on the amino group of adenine. This is consistent with the photoelectron imaging: excitation to the 1ππ* states leads to an aligned ensemble distributed predominantly parallel to the long axis of adenine; the subsequent electron tunneling site is along this axis; and the negatively charged phosphate groups guide the outgoing electron mostly along this axis at long range. Imaging of electron tunneling from polyanions combined with computational chemistry may offer a general route for probing the intrinsic photo-oxidation site and dynamics as well as the overall structure of complex isolated species." @default.
- W3083323213 created "2020-09-11" @default.
- W3083323213 creator A5008682258 @default.
- W3083323213 creator A5045188370 @default.
- W3083323213 creator A5058363958 @default.
- W3083323213 creator A5064556498 @default.
- W3083323213 date "2020-09-04" @default.
- W3083323213 modified "2023-10-05" @default.
- W3083323213 title "Site-Specific Photo-oxidation of the Isolated Adenosine-5′-triphosphate Dianion Determined by Photoelectron Imaging" @default.
- W3083323213 cites W1663103339 @default.
- W3083323213 cites W182381116 @default.
- W3083323213 cites W1878606291 @default.
- W3083323213 cites W1909719340 @default.
- W3083323213 cites W1967167452 @default.
- W3083323213 cites W1971290862 @default.
- W3083323213 cites W1975928382 @default.
- W3083323213 cites W1976530061 @default.
- W3083323213 cites W1986259145 @default.
- W3083323213 cites W1988215922 @default.
- W3083323213 cites W1990345925 @default.
- W3083323213 cites W1993077801 @default.
- W3083323213 cites W1993340236 @default.
- W3083323213 cites W1995055752 @default.
- W3083323213 cites W2014805389 @default.
- W3083323213 cites W2015404499 @default.
- W3083323213 cites W2016679914 @default.
- W3083323213 cites W2023271753 @default.
- W3083323213 cites W2031548212 @default.
- W3083323213 cites W2034162312 @default.
- W3083323213 cites W2036592820 @default.
- W3083323213 cites W2038805482 @default.
- W3083323213 cites W2040207297 @default.
- W3083323213 cites W2041652527 @default.
- W3083323213 cites W2045299779 @default.
- W3083323213 cites W2064018996 @default.
- W3083323213 cites W2068241704 @default.
- W3083323213 cites W2068649704 @default.
- W3083323213 cites W2070257738 @default.
- W3083323213 cites W2070522574 @default.
- W3083323213 cites W2071824676 @default.
- W3083323213 cites W2073028740 @default.
- W3083323213 cites W2079783681 @default.
- W3083323213 cites W2081034737 @default.
- W3083323213 cites W2082691688 @default.
- W3083323213 cites W2086526873 @default.
- W3083323213 cites W2088350255 @default.
- W3083323213 cites W2089174293 @default.
- W3083323213 cites W2095141485 @default.
- W3083323213 cites W2101579153 @default.
- W3083323213 cites W2119547517 @default.
- W3083323213 cites W2120411267 @default.
- W3083323213 cites W2142882197 @default.
- W3083323213 cites W2143981217 @default.
- W3083323213 cites W2147558823 @default.
- W3083323213 cites W2156808572 @default.
- W3083323213 cites W2167377693 @default.
- W3083323213 cites W2170812193 @default.
- W3083323213 cites W2205176688 @default.
- W3083323213 cites W2281143149 @default.
- W3083323213 cites W2326221197 @default.
- W3083323213 cites W2328572285 @default.
- W3083323213 cites W2334492676 @default.
- W3083323213 cites W2584696766 @default.
- W3083323213 cites W2616240835 @default.
- W3083323213 cites W2837803169 @default.
- W3083323213 cites W2898308660 @default.
- W3083323213 cites W2952681572 @default.
- W3083323213 cites W3100844675 @default.
- W3083323213 cites W3104846374 @default.
- W3083323213 cites W4211182504 @default.
- W3083323213 cites W4253501541 @default.
- W3083323213 doi "https://doi.org/10.1021/acs.jpclett.0c02089" @default.
- W3083323213 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32886886" @default.
- W3083323213 hasPublicationYear "2020" @default.
- W3083323213 type Work @default.
- W3083323213 sameAs 3083323213 @default.
- W3083323213 citedByCount "7" @default.
- W3083323213 countsByYear W30833232132021 @default.
- W3083323213 countsByYear W30833232132022 @default.
- W3083323213 countsByYear W30833232132023 @default.
- W3083323213 crossrefType "journal-article" @default.
- W3083323213 hasAuthorship W3083323213A5008682258 @default.
- W3083323213 hasAuthorship W3083323213A5045188370 @default.
- W3083323213 hasAuthorship W3083323213A5058363958 @default.
- W3083323213 hasAuthorship W3083323213A5064556498 @default.
- W3083323213 hasBestOaLocation W30833232132 @default.
- W3083323213 hasConcept C120398109 @default.
- W3083323213 hasConcept C121332964 @default.
- W3083323213 hasConcept C147120987 @default.
- W3083323213 hasConcept C181500209 @default.
- W3083323213 hasConcept C184779094 @default.
- W3083323213 hasConcept C185592680 @default.
- W3083323213 hasConcept C26873012 @default.
- W3083323213 hasConcept C62520636 @default.
- W3083323213 hasConcept C83581075 @default.
- W3083323213 hasConceptScore W3083323213C120398109 @default.
- W3083323213 hasConceptScore W3083323213C121332964 @default.
- W3083323213 hasConceptScore W3083323213C147120987 @default.