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• W3083719703 endingPage "42733" @default.
• W3083719703 startingPage "42723" @default.
• W3083719703 abstract "Cu, Al, and 316L stainless steel are the main components of the current collectors and coin-type cells used in the characterization of potassium-ion battery (KIB) materials and are expected to be electrochemically inactive. Herein, their electrochemical stabilities in a nonaqueous potassium-bis(fluorosulfonyl)imide (KFSI)-based electrolyte are investigated. In dynamic- and transient-mode polarization, passivation of each metal is observed to occur below 3.9, 3.8, and 4.05 V versus K+/K for Cu, Al, and 316L stainless steel, respectively, which are considered the threshold potentials. The composition of the passive layers of each metal is determined using time-of-flight secondary-ion mass spectrometry. The passive layers of Cu and Al consist of Cu–O (CuO or Cu2O) and Al–O (Al2O3), respectively, and 316L stainless steel is passivated with an outermost Cr–F (CrF3) layer and an inner Cr–O (Cr2O3) layer. Above the threshold potentials, however, severe corrosion of each metal occurs accompanied by the dissolution of metal ions, which could affect the reliability of experimental results for KIBs using KFSI-based electrolytes." @default.
• W3083719703 created "2020-09-11" @default.
• W3083719703 creator A5046351087 @default.
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• W3083719703 date "2020-09-04" @default.
• W3083719703 modified "2023-10-16" @default.
• W3083719703 title "High-Voltage Stability in KFSI Nonaqueous Carbonate Solutions for Potassium-Ion Batteries: Current Collectors and Coin-Cell Components" @default.
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• W3083719703 doi "https://doi.org/10.1021/acsami.0c10471" @default.
• W3083719703 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32883076" @default.
• W3083719703 hasPublicationYear "2020" @default.
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