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- W3083850104 endingPage "12859" @default.
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- W3083850104 abstract "The structure and sequence elucidation of complex homo- and copolymers is key for further understanding polymers, polymer synthesis, and polymer interactions in biological processes. In this contribution, poly(dimethylacrylamide) homo- and dimethylacrylamide/4-acryloylmorpholine block copolymers were synthesized and analyzed by electron capture dissociation (ECD) and Fourier transform ion cyclotron resonance (FT-ICR) tandem mass spectrometry. Double-resonance experiments were carried out, providing a better understanding of the fragmentation process. A novel radical dissociation process is presented, and electron capture caused a specific cleavage at the terminal butyl-trithiocarbonate group, which initiated a free radical dissociation process." @default.
- W3083850104 created "2020-09-14" @default.
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- W3083850104 date "2020-09-09" @default.
- W3083850104 modified "2023-10-09" @default.
- W3083850104 title "Electron Capture Dissociation of Trithiocarbonate-Terminated Acrylamide Homo- and Copolymers: A Terminus-Directed Mechanism?" @default.
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- W3083850104 doi "https://doi.org/10.1021/acs.analchem.0c01224" @default.
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