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• W3083856858 abstract "Abstract As the only stable binary compound formed between an alkali metal and nitrogen, lithium nitride possesses remarkable properties and is a model material for energy applications involving the transport of lithium ions. Following a materials design principle drawn from broad structural analogies to hexagonal graphene and boron nitride, we demonstrate that such low dimensional structures can also be formed from an s-block element and nitrogen. Both one- and two-dimensional nanostructures of lithium nitride, Li 3 N, can be grown despite the absence of an equivalent van der Waals gap. Lithium-ion diffusion is enhanced compared to the bulk compound, yielding materials with exceptional ionic mobility. Li 3 N demonstrates the conceptual assembly of ionic inorganic nanostructures from monolayers without the requirement of a van der Waals gap. Computational studies reveal an electronic structure mediated by the number of Li-N layers, with a transition from a bulk narrow-bandgap semiconductor to a metal at the nanoscale." @default.
• W3083856858 created "2020-09-14" @default.
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• W3083856858 date "2020-09-08" @default.
• W3083856858 modified "2023-10-17" @default.
• W3083856858 title "Low dimensional nanostructures of fast ion conducting lithium nitride" @default.
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• W3083856858 doi "https://doi.org/10.1038/s41467-020-17951-6" @default.
• W3083856858 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7479578" @default.
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