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• W3083990384 endingPage "104504" @default.
• W3083990384 startingPage "104504" @default.
• W3083990384 abstract "Thermodynamic or density scaling is applied to thermal conductivity (λ) data from the literature for the model Lennard-Jones (12-6) fluid; the noble gases neon to xenon; nitrogen, ethene, and carbon dioxide as examples of linear molecules; the quasi-spherical molecules methane and carbon tetrachloride; the flexible chain molecules n-hexane and n-octane; the planar toluene and m-xylene; the cyclic methylcyclohexane; the polar R132a and chlorobenzene; and ammonia and methanol as H-bonded fluids. Only data expressed as Rosenfeld reduced properties could be scaled successfully. Two different methods were used to obtain the scaling parameter γ, one based on polynomial fits to the group (TVγ) and the other based on the Avramov equation. The two methods agree well, except for λ of CCl4. γ for the thermal conductivity is similar to those for the viscosity and self-diffusion coefficient for the smaller molecules. It is significantly larger for the Lennard-Jones fluid, possibly due to a different dependence on packing fraction, and much larger for polyatomic molecules where heat transfer through internal modes may have an additional effect. Methanol and ammonia, where energy can be transmitted through intermolecular hydrogen bonding, could not be scaled. This work is intended as a practical attempt to examine thermodynamic scaling of the thermal conductivity of real fluids. The divergence of the scaling parameters for different properties is unexpected, suggesting that refinement of theory is required to rationalize this result. For the Lennard-Jones fluid, the Ohtori–Iishi version of the Stokes–Einstein–Sutherland relation applies at high densities in the liquid and supercritical region." @default.
• W3083990384 created "2020-09-14" @default.
• W3083990384 creator A5014628803 @default.
• W3083990384 date "2020-09-14" @default.
• W3083990384 modified "2023-09-25" @default.
• W3083990384 title "Thermodynamic or density scaling of the thermal conductivity of liquids" @default.
• W3083990384 cites W101648405 @default.
• W3083990384 cites W1588197410 @default.
• W3083990384 cites W1637101347 @default.
• W3083990384 cites W1660120183 @default.
• W3083990384 cites W1670288452 @default.
• W3083990384 cites W1965260481 @default.
• W3083990384 cites W1971747501 @default.
• W3083990384 cites W1972112902 @default.
• W3083990384 cites W1972865814 @default.
• W3083990384 cites W1974639419 @default.
• W3083990384 cites W1975264298 @default.
• W3083990384 cites W1979382363 @default.
• W3083990384 cites W1981138816 @default.
• W3083990384 cites W1981941889 @default.
• W3083990384 cites W1982387598 @default.
• W3083990384 cites W1983118500 @default.
• W3083990384 cites W1983581148 @default.
• W3083990384 cites W1987223497 @default.
• W3083990384 cites W1987880864 @default.
• W3083990384 cites W1988100940 @default.
• W3083990384 cites W1989042937 @default.
• W3083990384 cites W1991509643 @default.
• W3083990384 cites W1992540127 @default.
• W3083990384 cites W1993070045 @default.
• W3083990384 cites W1996022768 @default.
• W3083990384 cites W1996324780 @default.
• W3083990384 cites W1997113324 @default.
• W3083990384 cites W1999110497 @default.
• W3083990384 cites W2000574747 @default.
• W3083990384 cites W2002459859 @default.
• W3083990384 cites W2002589735 @default.
• W3083990384 cites W2002645538 @default.
• W3083990384 cites W2006061247 @default.
• W3083990384 cites W2007886094 @default.
• W3083990384 cites W2008770057 @default.
• W3083990384 cites W2010311775 @default.
• W3083990384 cites W2011987422 @default.
• W3083990384 cites W2013788622 @default.
• W3083990384 cites W2014384115 @default.
• W3083990384 cites W2017334920 @default.
• W3083990384 cites W2018048921 @default.
• W3083990384 cites W2018470441 @default.
• W3083990384 cites W2018527601 @default.
• W3083990384 cites W2018742501 @default.
• W3083990384 cites W2018858341 @default.
• W3083990384 cites W2019514865 @default.
• W3083990384 cites W2020309531 @default.
• W3083990384 cites W2020797326 @default.
• W3083990384 cites W2022045300 @default.
• W3083990384 cites W2022955688 @default.
• W3083990384 cites W2029540202 @default.
• W3083990384 cites W2029575037 @default.
• W3083990384 cites W2030721314 @default.
• W3083990384 cites W2030765885 @default.
• W3083990384 cites W2035281018 @default.
• W3083990384 cites W2035719223 @default.
• W3083990384 cites W2036791824 @default.
• W3083990384 cites W2037183985 @default.
• W3083990384 cites W2037967455 @default.
• W3083990384 cites W2038747920 @default.
• W3083990384 cites W2041422504 @default.
• W3083990384 cites W2041517673 @default.
• W3083990384 cites W2045646743 @default.
• W3083990384 cites W2046340076 @default.
• W3083990384 cites W2052537108 @default.
• W3083990384 cites W2052643653 @default.
• W3083990384 cites W2052964160 @default.
• W3083990384 cites W2054554331 @default.
• W3083990384 cites W2055611713 @default.
• W3083990384 cites W2056423248 @default.
• W3083990384 cites W2058506928 @default.
• W3083990384 cites W2059067694 @default.
• W3083990384 cites W2059473891 @default.
• W3083990384 cites W2059805298 @default.
• W3083990384 cites W2060052038 @default.
• W3083990384 cites W2060246957 @default.
• W3083990384 cites W2061273608 @default.
• W3083990384 cites W2061848642 @default.
• W3083990384 cites W2064202919 @default.
• W3083990384 cites W2066502472 @default.
• W3083990384 cites W2068569597 @default.
• W3083990384 cites W2070455079 @default.
• W3083990384 cites W2070527296 @default.
• W3083990384 cites W2071785970 @default.
• W3083990384 cites W2072304311 @default.
• W3083990384 cites W2072485626 @default.
• W3083990384 cites W2072641211 @default.
• W3083990384 cites W2074723317 @default.
• W3083990384 cites W2075698919 @default.
• W3083990384 cites W2075760383 @default.
• W3083990384 cites W2075887962 @default.
• W3083990384 cites W2076843326 @default.

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