Matches in SemOpenAlex for { <https://semopenalex.org/work/W3084028053> ?p ?o ?g. }
- W3084028053 endingPage "17139" @default.
- W3084028053 startingPage "17131" @default.
- W3084028053 abstract "Earth-abundant metal pincer complexes have played an important role in homogeneous catalysis during the last ten years. Yet, despite intense research efforts, the synthesis of iron PCcarbeneP pincer complexes has so far remained elusive. Here we report the synthesis of the first PCNHCP functionalized iron complex [(PCNHCP)FeCl2] (1) and the reactivity of the corresponding trans-dihydride iron(II) dinitrogen complex [(PCNHCP)Fe(H)2N2)] (2). Complex 2 is stable under an atmosphere of N2 and is highly active for hydrogen isotope exchange at (hetero)aromatic hydrocarbons under mild conditions (50 °C, N2). With benzene-d6 as the deuterium source, easily reducible functional groups such as esters and amides are well tolerated, contributing to the overall wide substrate scope (e.g., halides, ethers, and amines). DFT studies suggest a complex assisted σ-bond metathesis pathway for C(sp2)–H bond activation, which is further discussed in this study." @default.
- W3084028053 created "2020-09-14" @default.
- W3084028053 creator A5002354165 @default.
- W3084028053 creator A5022394866 @default.
- W3084028053 creator A5029797647 @default.
- W3084028053 creator A5038775587 @default.
- W3084028053 creator A5076042321 @default.
- W3084028053 date "2020-09-09" @default.
- W3084028053 modified "2023-10-13" @default.
- W3084028053 title "Facile H/D Exchange at (Hetero)Aromatic Hydrocarbons Catalyzed by a Stable Trans-Dihydride N-Heterocyclic Carbene (NHC) Iron Complex" @default.
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