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• W3084097927 abstract "The synthetic protocols, structural aspects, and spectroscopic aspects of mononuclear pseudostannatranes possessing a [4.4.3.01,5]tridecane cage have been reported. A tripodal ligand N(CH2CH2OH){CH2(2-t-Bu-4-Me-C6H2OH)}2 (H3L) having unsymmetrical arms was reacted with n-butyltrichlorostannane, phenyltrichlorostannane, and tin tetrachloride under different solvent systems to obtain pseudostannatranes (1–3). The reaction of n-butyltrichlorostannane and the ligand in CH3OH/Na/THF yielded an aqua complex of pseudostannatrane [LSnBu(H2O)] (1a), which was crystallized as its acetone solvate (i.e 1a·Me2CO). However, the same reactants yielded methanol complex [LSnBu(CH3OH)] (1b) when the reaction was carried out in the NaOCH3/C2H5OH system. Similarly, the reaction of phenyltrichlorostannane and the ligand under these solvent systems yielded pseudostannatranes, i.e., an aqua complex [LSnPh(H2O)] (2a) and a methanol complex [LSnPh(CH3OH)] (2b) (where 2a was crystallized as 2a·Me2CO). The reaction of tin tetrachloride and the ligand in the Et3N/THF system resulted in the formation of pseudostannatrane [LHSnCl2] (3). A similar product was isolated as its triethylamine solvate (3·NEt3) due to the disproportion reaction when PhSnCl3 was reacted with the ligand in the Et3N/C6H5CH3 system, which demonstrates the first report on the reverse Kocheshkov reaction in pseudostannatranes. The experimental findings on the formation of 3·NEt3 due to the reverse Kocheshkov reaction have been corroborated with 119Sn NMR spectroscopy and density functional calculations that provide insightful information about the underlying details of the reaction route." @default.
• W3084097927 created "2020-09-14" @default.
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• W3084097927 date "2020-09-09" @default.
• W3084097927 modified "2023-10-03" @default.
• W3084097927 title "Mononuclear Pseudostannatranes Possessing Unsymmetrical [4.4.3.0^1,5]Tridecane Cage: Experimental and Theoretical Aspects of Reverse Kocheshkov Reaction in Phenyl Pseudostannatrane" @default.
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• W3084097927 doi "https://doi.org/10.1021/acs.inorgchem.0c01202" @default.
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