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- W3084202801 abstract "In this paper, we present a short and convenient synthesis of the natural product Harzialactone A and its three stereoisomers. In a three‐step synthesis starting from cheap and commercially available benzaldehyde, we created the small polyketidic compound with full control over its two stereogenic centers. To this end, we employed a chiral building block previously described by us, introducing the first stereogenic center through a Horner–Wittig reaction. The second stereogenic center was installed via stereocontrolled syn ‐ or anti ‐reduction with the corresponding β‐hydroxy ketone intermediates. Upon ozonolysis followed by oxidation the natural product and its stereovariants were produced with excellent enantio‐ and diastereopurities." @default.
- W3084202801 created "2020-09-14" @default.
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- W3084202801 date "2020-09-08" @default.
- W3084202801 modified "2023-09-26" @default.
- W3084202801 title "Stereocontrolled Synthesis of Harzialactone A and Its Three Stereoisomers by Use of Standardized Polyketide Building Blocks" @default.
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- W3084202801 doi "https://doi.org/10.1002/ejoc.202001046" @default.
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