Matches in SemOpenAlex for { <https://semopenalex.org/work/W3084232278> ?p ?o ?g. }
- W3084232278 endingPage "13280" @default.
- W3084232278 startingPage "13270" @default.
- W3084232278 abstract "Adducts of bismuth trihalides BiX3 (X = Cl, Br, I) and the PS3 ligand (PS3 = P(C6H4-o-CH2SCH3)3) react with HCl to form inorganic/organic hybrids with the general formula [HPS3BiX4]2. On the basis of their solid-state structures determined by single-crystal X-ray diffraction, these compounds exhibit discrete bis-zwitterionic assemblies consisting of two phosphonium units [HPS3]+ linked to a central dibismuthate core [Bi2X8]2– via S→Bi dative interactions. Remarkably, the phosphorus center of the PS3 ligand undergoes protonation with hydrochloric acid. This is in stark contrast to the protonation of phosphines commonly observed with hydrogen halides resulting in equilibrium. To understand the important factors in this protonation reaction, 31P NMR experiments and DFT computations have been performed. Furthermore, the dibismuthate linker was utilized to obtain the coordination polymer {[AgPS3BiCl3(OTf)]2(CH3CN)2}∞, in which dicationic [Ag(PS3)]22+ macrocycles containing five-coordinate silver centers connect the dianionic [Bi2Cl6(OTf)2]2– dibismuthate fragments. The bonding situation in these dibismuthates has been investigated by single-crystal X-ray diffraction and DFT calculations (NBO analysis, AIM analysis, charge distribution)." @default.
- W3084232278 created "2020-09-14" @default.
- W3084232278 creator A5025163552 @default.
- W3084232278 creator A5030365339 @default.
- W3084232278 creator A5046752534 @default.
- W3084232278 creator A5070762807 @default.
- W3084232278 date "2020-09-08" @default.
- W3084232278 modified "2023-10-18" @default.
- W3084232278 title "Dibismuthates as Linking Units for Bis-Zwitterions and Coordination Polymers" @default.
- W3084232278 cites W1433298236 @default.
- W3084232278 cites W1903937986 @default.
- W3084232278 cites W1963725212 @default.
- W3084232278 cites W1967339486 @default.
- W3084232278 cites W1968849472 @default.
- W3084232278 cites W1970067297 @default.
- W3084232278 cites W1972425787 @default.
- W3084232278 cites W1990756777 @default.
- W3084232278 cites W1992331313 @default.
- W3084232278 cites W1993922358 @default.
- W3084232278 cites W1998049497 @default.
- W3084232278 cites W2003837685 @default.
- W3084232278 cites W2004406262 @default.
- W3084232278 cites W2004437497 @default.
- W3084232278 cites W2006889778 @default.
- W3084232278 cites W2008358810 @default.
- W3084232278 cites W2008950472 @default.
- W3084232278 cites W2014636858 @default.
- W3084232278 cites W2015112371 @default.
- W3084232278 cites W2016008074 @default.
- W3084232278 cites W2019340730 @default.
- W3084232278 cites W2023644357 @default.
- W3084232278 cites W2024474938 @default.
- W3084232278 cites W2025243023 @default.
- W3084232278 cites W2026345329 @default.
- W3084232278 cites W2030871702 @default.
- W3084232278 cites W2035374636 @default.
- W3084232278 cites W2035740866 @default.
- W3084232278 cites W2038071113 @default.
- W3084232278 cites W2041516227 @default.
- W3084232278 cites W2047396213 @default.
- W3084232278 cites W2051379572 @default.
- W3084232278 cites W2052969123 @default.
- W3084232278 cites W2053184539 @default.
- W3084232278 cites W2055581741 @default.
- W3084232278 cites W2063404390 @default.
- W3084232278 cites W2069054275 @default.
- W3084232278 cites W2070764285 @default.
- W3084232278 cites W2077667250 @default.
- W3084232278 cites W2079907682 @default.
- W3084232278 cites W2087679771 @default.
- W3084232278 cites W2090035594 @default.
- W3084232278 cites W2091003589 @default.
- W3084232278 cites W2091574821 @default.
- W3084232278 cites W2095026358 @default.
- W3084232278 cites W2101741054 @default.
- W3084232278 cites W2105249240 @default.
- W3084232278 cites W2105459013 @default.
- W3084232278 cites W2113851763 @default.
- W3084232278 cites W2116694786 @default.
- W3084232278 cites W2126383912 @default.
- W3084232278 cites W2130684744 @default.
- W3084232278 cites W2134850892 @default.
- W3084232278 cites W2147500863 @default.
- W3084232278 cites W2154872844 @default.
- W3084232278 cites W2160276431 @default.
- W3084232278 cites W2160419072 @default.
- W3084232278 cites W2163844500 @default.
- W3084232278 cites W2174948835 @default.
- W3084232278 cites W2216893367 @default.
- W3084232278 cites W2314827001 @default.
- W3084232278 cites W2315190157 @default.
- W3084232278 cites W2325376455 @default.
- W3084232278 cites W2332128542 @default.
- W3084232278 cites W2333130162 @default.
- W3084232278 cites W2333525916 @default.
- W3084232278 cites W2564506363 @default.
- W3084232278 cites W2591619666 @default.
- W3084232278 cites W2605143605 @default.
- W3084232278 cites W2623757051 @default.
- W3084232278 cites W2651691458 @default.
- W3084232278 cites W2659298787 @default.
- W3084232278 cites W2732839448 @default.
- W3084232278 cites W2736647697 @default.
- W3084232278 cites W2744085873 @default.
- W3084232278 cites W2744602331 @default.
- W3084232278 cites W2761962988 @default.
- W3084232278 cites W2779324086 @default.
- W3084232278 cites W2780896444 @default.
- W3084232278 cites W2802794921 @default.
- W3084232278 cites W2810748258 @default.
- W3084232278 cites W2889146687 @default.
- W3084232278 cites W2892288370 @default.
- W3084232278 cites W2895237713 @default.
- W3084232278 cites W2906876630 @default.
- W3084232278 cites W2913013088 @default.
- W3084232278 cites W2942353297 @default.
- W3084232278 cites W2965701820 @default.
- W3084232278 cites W2989132478 @default.