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- W3084361247 abstract "A previously unreported 1D iridate, K₃Ir₂O₆, has been grown by a flux method in O₂-rich environment, and its crystal structure was determined via single crystal structural analysis. It exhibits straight chains of face-sharing [IrO₆] octahedra, which are arranged along the crystallographic c axis, separated by nonmagnetic K ions. No magnetic transitions are observed during measured range, and the material is electrically insulating. Potentially interesting electronic behavior for K₃Ir₂O₆ is supported by electronic structure calculations. A structurally related material, K₁₆.₃Ir₈O₃₀, which displays similar fundamental geometric units but in a different spatial arrangement—zigzag chains—based on edge and face sharing [IrO₆] octahedra, is also reported. Both materials are of interest for probing the properties of a 1D system with strong spin–orbit coupling." @default.
- W3084361247 created "2020-09-14" @default.
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- W3084361247 date "2020-01-01" @default.
- W3084361247 modified "2023-09-23" @default.
- W3084361247 title "K₃Ir₂O₆ and K₁₆.₃Ir₈O₃₀, Low-Dimensional Iridates with Infinite IrO₆ Chains" @default.
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