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- W3085907407 abstract "CuZnO-ZrO2-C was prepared by a co-precipitation method. For comparison, CuZnO-ZrO2-PC and CuZnO-ZrO2-CP were prepared by glow discharge plasma. The catalysts were characterized via the XRD, N2 adsorption-desorption, TEM, SEM, EDS, XPS, CO2-TPD and H2-TPR techniques. The catalysts were comparatively investigated for CO2 conversion and methanol selectivity in a fixed-bed reactor under the condition of 2 MPa, 250 °C, H2/CO2 = 3/1 and GHSV = 12 000 mL g-1 h-1. The results showed that the activities of the catalysts increased in the order of CuZnO-ZrO2-PC > CuZnO-ZrO2-CP > CuZnO-ZrO2-C. Moreover, the CO2 conversion of CuZnO-ZrO2-C increased by 38.9% via treatment with glow discharge plasma. The results are well explained based on the CO2-TPD and H2-TPR characterizations of the catalysts." @default.
- W3085907407 created "2020-09-21" @default.
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- W3085907407 date "2020-01-01" @default.
- W3085907407 modified "2023-10-12" @default.
- W3085907407 title "Highly selective conversion of CO<sub>2</sub> to methanol on the CuZnO–ZrO<sub>2</sub> solid solution with the assistance of plasma" @default.
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- W3085907407 doi "https://doi.org/10.1039/d0ra00961j" @default.
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